14.7 g of solid sodium hydrogen carbonate (
Assume that all
What is the enthalpy of reaction, in kJ mol
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14.7 g of solid sodium hydrogen carbonate (
Assume that all
What is the enthalpy of reaction, in kJ mol
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Find mass of
Mass of the final solution
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100.00 mL of 2.00 mol L¯1
10.0 g of solid
Assuming no energy loss to the environment, calculate the maximum temperature reached by the solution. (5 marks)
Use the following information in your calculations.
Citric acid reacts with sodium hydroxide according to the following chemical equation:
Various volumes of 1.0 mol L¯1 citric acid solution were mixed with 8.0 mL of a sodium hydroxide solution of unknown concentration and sufficient deionised water added to make the total volume of the resulting solution 14.0 mL. The change in temperature of each solution was measured.
The data are given in the table.
By graphing the data in the table and performing relevant calculations, determine the concentration of the sodium hydroxide solution. (7 marks)
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Students conducted an experiment to determine
The data from one student are shown in the table below.
Assume that all the solutions have the same specific heat capacity as water.
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a.
Therefore, 2800 J of heat energy is released in this experiment (assuming no energy loss).
b.
The molar enthalpies of neutralisation of three reactions are given.
Reaction 1:
Reaction 2:
Reaction 3:
Explain why the first two reactions have the same enthalpy value but the third reaction has a different value. (4 marks)
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→ Reaction 1 and reaction 2 are both neutralisation reactions between strong acids and strong bases. These reactions completely ionise in solution when added to water.
→ Both reactions have the same net ionic equation:
→ Therefore, the enthalpy values obtained are the same for both reactions.
→ In reaction 3,
→ As the reaction continues,
→ The bond-breaking is an endothermic process and thus will consume energy to break the bonds. As a result, the overall reaction is less exothermic than reaction 1 and reaction 2.
→ Reaction 1 and reaction 2 are both neutralisation reactions between strong acids and strong bases. These reactions completely ionise in solution when added to water.
→ Both reactions have the same net ionic equation:
→ Therefore, the enthalpy values obtained are the same for both reactions.
→ In reaction 3,
→ As the reaction continues,
→ The bond-breaking is an endothermic process and thus will consume energy to break the bonds. As a result, the overall reaction is less exothermic than reaction 1 and reaction 2.