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CHEMISTRY, M8 2024 HSC 9 MC

Which of the following is the mass spectrum of ethanamine?
 

 

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→ The molar mass of ethanamine, , is 45.086 g mol

→ The peak with the largest mass to charge ratio displays the molar mass of the substance.

→ Therefore, the parent ion peak will be at 45.

CHEMISTRY, M8 2021 VCE 7*

Two students are given a homework assignment that involves analysing a set of spectra and identifying an unknown compound. The unknown compound is one of the molecules shown below.
 

The spectrum of the unknown compound is shown below.
 

  1. Based on the number of peaks in the spectrum above, which compound – or – could be eliminated as the unknown compound?   (1 mark)

  2. The infra-red (IR) spectrum of the unknown compound is shown below.
     

  1. Identify which of the five compounds (1 or more) can be eliminated on the basis of the IR spectrum. Justify your answer using data from the IR spectrum.   (3 marks)

  2. The mass spectrum of the unknown compound is shown below.
     

  1. Write the chemical formula of the species that produces a peak at m/z = 43.   (1 mark)

  2. Explain why one molecule can produce multiple peaks on a mass spectrum.   (2 mark)

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a.    → The shows 4 different carbon environments.

→ Compound has 5 unique carbon environments and can be eliminated.
 

b.    → Compounds and can be eliminated.

→ Compounds and both don’t have an alcohol group, however the IR spectrum clearly shows an alcohol group with an absorbance at 3500 cm.

→ Compound contains an acid group whereas the IR spectrum shows an alcohol group at 3500 cm. There is no evidence of a broad acid group between 2500–3000 cm.
 

c.i.  → The unknown compound is compound .

→ The chemical species are fragments of the original compound with a positive charge.

→ The chemical formulas could include or
 

 ii.   → Ions of that molecule must be formed to produce peaks on the mass spectrum.

→ Organic compounds can be split up into numerous different ions when producing fragment patterns leading to multiple different peaks on the mass spectrum.

Show Worked Solution

a.    → The shows 4 different carbon environments.

→ Compound has 5 unique carbon environments and can be eliminated.
 

b.    → Compounds and can be eliminated.

→ Compounds and both don’t have an alcohol group, however the IR spectrum clearly shows an alcohol group with an absorbance at 3500 cm.

→ Compound contains an acid group whereas the IR spectrum shows an alcohol group at 3500 cm. There is no evidence of a broad acid group between 2500–3000 cm.
 

♦ Mean mark (b) 43%.
COMMENT: Recognise the difference between OH alcohols and OH acid groups.

c.i.  → The unknown compound is compound .

→ The chemical species are fragments of the original compound with a positive charge.

→ The chemical formulas could include or

♦ Mean mark (c.i.) 50%.
COMMENT: Ions require a positive charge.

 ii.   → Ions of that molecule must be formed to produce peaks on the mass spectrum.

→ Organic compounds can be split up into numerous different ions when producing fragment patterns leading to multiple different peaks on the mass spectrum.

♦ Mean mark (c.ii.) 39%.

CHEMISTRY, M8 2023 VCE 29 MC

Which one of the following statements about mass spectrometry is always correct?

  1. The relative molecular mass of a molecule is determined from the base peak.
  2. The peaks in a mass spectrum are caused by the presence of different isotopes.
  3. The base peak is formed when an uncharged species is removed from the molecule.
  4. The height of each peak in the mass spectrum is measured relative to the height of the base peak.
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→ The relative molecular mass of a molecule is determined from the peak with the largest m/z ratio (eliminate ).

→ The peaks in a mass spectrum is caused by the molecules splitting up into different ions as they are bombarded with electrons. Some peaks that differ by a value of 1 are caused by the presence of different isotopes but this is not for all peaks (eliminate ).

→ All peaks on the mass spectrometry graph are charged ions (eliminate ).

→ The base peak is the largest peak on a mass spectrometry graph and therefore the abundances of each peak are relative to the height of the base peak.

♦ Mean mark 46%.

CHEMISTRY, M8 2023 HSC 19 MC

The diagram shows a simplified mass spectrum for butan-2-one.
 

Which equation best represents the process that produces the particle responsible for the peak at m/z 43 ?

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→ The peaks in mass spectra represent fragments of organic molecules.

→ Mass Spectrometers can only detect charged particles meaning the peak at 43 m/z could only represent:

  or 

→ The m/z ratio is indicative of a fragment’s molecular weight which corresponds to

♦ Mean mark 51%.

CHEMISTRY, M8 2023 HSC 28

Alkene undergoes an addition reaction with chlorine gas to form compound .

  1. Describe a chemical test that could be done in a school laboratory to confirm that is an alkene. Include expected observations in your answer.  (2 marks)
  1. Compound was analysed and found to contain approximately 32% carbon by mass. The mass spectrum of compound is shown. 

  1. Provide a structural formula for compound . Support your answer with calculations.  (3 marks)
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a.    Chemical test for an alkene

→ Prepare a sample of alkene in a clean test tube.

→ Add a few drops of bromine water to the sample.

→ The bromine water will be decolourised if is an alkene.

Other correct answers could include:

→ The addition of potassium permanganate will also be decolourised by if it is an alkene.

 
b.   Molecular ion is present at m/z = 114

Atomic mass of (in compound ) = 32% × 114 = 36

atoms in 1 molecule of R = 36 ÷ 12 = 3

Mass (non-) = 114 – 36 = 78

Two atoms of are in compound

has the formula , and structure:
 

Show Worked Solution

a.    Chemical test for an alkene

→ Prepare a sample of alkene in a clean test tube.

→ Add a few drops of bromine water to the sample.

→ The bromine water will be decolourised if is an alkene.

Other correct answers could include:

→ The addition of potassium permanganate will also be decolourised by if it is an alkene.

 
b.   Molecular ion is present at m/z = 114

Atomic mass of (in compound ) = 32% × 114 = 36

atoms in 1 molecule of R = 36 ÷ 12 = 3

Mass (non-) = 114 – 36 = 78

Two atoms of are in compound

has the formula , and structure:
 

♦ Mean mark (b) 53%.

CHEMISTRY, M8 EQ-Bank 22

  1. The diagram is a schematic representation of a mass spectrometer.
     

  1. Name and outline the function of the part labelled in the diagram.   (2 marks)

  2. Outline the advantages of using mass spectrometry for analysis of a compound.   (3 marks)

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a.    → is a magnet.

→ It bends the charged particles that are accelerated through an electric field and directed through it.

→ The amount of bending can then be used to distinguish between and identify the particles/ions.
 

b.   Advantages of mass spectrometry

→ The mass spectrometer can identify the mass/charge ratio of ions that pass through it. This data can then be used to identify components of a mixture or components in a compound.

→ Different isotopes of elements in a compound can be identified by mass spectrometers. This allows the compound to be matched to a sample.

→ Mass spectrometry can provide both qualitative and quantitative data on a compound.

→ Finally, mass spectrometers only require a small quantity of a compound to perform detailed analysis, as well as being fast and sensitive.

Show Worked Solution

a.    → is a magnet.

→ It bends the charged particles that are accelerated through an electric field and directed through it.

→ The amount of bending can then be used to distinguish between and identify the particles/ions.
 

b.   Advantages of mass spectrometry

→ The mass spectrometer can identify the mass/charge ratio of ions that pass through it. This data can then be used to identify components of a mixture or components in a compound.

→ Different isotopes of elements in a compound can be identified by mass spectrometers. This allows the compound to be matched to a sample.

→ Mass spectrometry can provide both qualitative and quantitative data on a compound.

→ Mass spectrometers only require a small quantity of a compound to perform detailed analysis, as well as being fast and sensitive.

CHEMISTRY, M8 EQ-Bank 21

The diagram shows the deflection paths of different ions through a mass spectrometer.
 

Account for the different deflection paths.   (3 marks)

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→ Mass spectrometers use an electric field to accelerate positively charged ions before passing them through a magnetic field.

→ Once in the magnetic field, the ions travel in a curved path, the direction of which depends on whether the ion is positively or negatively charged.

→ The amount of curvature is dependent on the speed at which the ion is travelling and its mass to charge ratio.

→ Lighter ions have less momentum and are deflected more strongly than heavier ions.

Show Worked Solution

→ Mass spectrometers use an electric field to accelerate positively charged ions before passing them through a magnetic field.

→ Once in the magnetic field, the ions travel in a curved path, the direction of which depends on whether the ion is positively or negatively charged.

→ The amount of curvature is dependent on the speed at which the ion is travelling and its mass to charge ratio.

→ Lighter ions have less momentum and are deflected more strongly than heavier ions.

CHEMISTRY, M8 2019 HSC 4 MC

The diagram shows the mass spectrum of an organic compound.
 

Which compound was analysed?

  1. Butan-1-amine
  2. Butanoic acid
  3. Ethanoic acid
  4. Iron sulfide
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→ The parent ion in the mass spectrum has a mass to charge ratio (m/z) of 88 that matches the molar mass of butanoic acid.

CHEMISTRY, M8 2020 HSC 21

The mass spectrum of an alkane is shown.
 

Use the information provided to identify the alkane and justify your choice.   (2 marks)

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→ The alkane is propane.

→ The mass spectrum has a molecular ion peak of 44, which indicates that the alkane is (propane).

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→ The alkane is propane.

→ The mass spectrum has a molecular ion peak of 44, which indicates that the alkane is (propane).

CHEMISTRY, M8 2020 HSC 1 MC

What is the function of the magnetic field in a mass spectrometer?

  1. It detects the mass of the particles.
  2. It deflects the stream of charged particles.
  3. It excites electrons to higher energy levels.
  4. It produces a stream of electrons that bombards the sample.
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Show Worked Solution

Magnetic fields cause charged particles to travel in a circular path.