How does diluting a 0.1 M solution of lactic acid,
pH | Percentage ionisation | |
A. | increase | decrease |
B. | increase | increase |
C. | decrease | increase |
D. | decrease | decrease |
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How does diluting a 0.1 M solution of lactic acid,
pH | Percentage ionisation | |
A. | increase | decrease |
B. | increase | increase |
C. | decrease | increase |
D. | decrease | decrease |
→ Ionisation of lactic acid:
→ Adding water decreases
→
→ Overall, the pH increases and the percentage ionisation increases.
Butanoic acid is the simplest carboxylic acid that is also classified as a fatty acid. Butanoic acid may be synthesised as outlined in the following reaction flow chart.
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i.
ii.
iii. butan-1-ol or 1-butanol
iv.
v.
i.
iii. butan-1-ol or 1-butanol
iv.
v.
A student mixed salicylic acid with ethanoic anhydride (acetic anhydride) in the presence of concentrated sulfuric acid. The products of this reaction were the painkilling drug aspirin (acetyl salicylic acid) and ethanoic acid.
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i.
ii. Sulphuric acid increases the rate of reaction by:
→ providing an alternative reaction pathway that involves a lower activation energy for the reagents.
→ this increases the likelihood of successful collisions.
i.
ii. Sulphuric acid increases the rate of reaction by:
→ providing an alternative reaction pathway that involves a lower activation energy for the reagents.
→ this increases the likelihood of successful collisions.
Methanol is a liquid fuel that is often used in racing cars. The thermochemical equation for its complete combustion is
Octane is a principal constituent of petrol, which is used in many motor vehicles. The thermochemical equation for
the complete combustion of octane is
The molar mass of methanol is 32 g mol
Consider option B:
→ 1 mole of
→
→ Heat energy of 1 gram
When ethene is mixed with chlorine in the presence of UV light, the following reaction takes place.
Reactions of organic compounds can be classified in a number of ways. The following list shows four possible classifications:
Which classification(s) applies to the reaction between ethene and chlorine?
Addition reaction:
→
Redox reaction:
→ The oxidation state of
→ In
→ In
→ The oxidation state of
What is the pH of a 0.0500 M solution of barium hydroxide,
Hydrogen sulfide, in solution, is a diprotic acid and ionises in two stages.
A student made two assumptions when estimating the pH of a
Assumption 1: The pH can be estimated by considering only the first ionisation reaction.
Assumption 2: The concentration of
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a. 1st assumption:
→
2nd assumption:
→
b.
c. Adding
→ Increases the
→ This increase causes the 1st ionisation equilibrium back to the left.
→ This left shift in the equilibrium decreases the
a. 1st assumption:
→
2nd assumption:
→
b. | ||
|
||
c. Adding
→ Increases the
→ This increase causes the 1st ionisation equilibrium back to the left.
→ This left shift in the equilibrium decreases the
The following table shows the value of the ionisation constant of pure water at various temperatures and at a constant pressure.
Given this data, which one of the following statements about pure water is correct?
→ Table shows that
→ Ionisation equation shifts right as temperature increases, causing an increase in
→ pH decreases as
→ pH of water = 7 at 25°C only (eliminate D).
A physics student comes across a river which runs north to south and has a current of 3 ms
The student starts on the west side of the river at point A and paddles a kayak at 5 ms
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a.
b.
a.
The student must turn 36.9
b. Using Pythagoras:
Below is a description of the motion of a runner. The motion can be divided into three stages.
Stage 1: Runner travels 120 metres south taking 20 seconds.
Stage 2: Runner turns west and travels at 5 ms
Stage 3: Runner travels directly back to their starting position.
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a.
b.
a. | ||
b. Stage 1 and Stage 2 displacement diagram:
Using Pythagoras:
The histogram below displays the distribution of skull width, in millimetres, for 46 female possums.
Question 1
The shape of the distribution is best described as
Question 2
The percentage of the 46 possums with a skull width of less than 55 mm is closest to
Question 3
The third quartile
The distribution’s centre is in the 56–57 group and if the possible outlier is disregarded, the tail of the distribution is spread more to the left → i.e. negatively skewed with possible outlier.
The 34.5th score lies between 57 and 58, therefore, 57.7.
A plane is travelling at 315 ms
The plane did not change direction and travelled 2.5 km while it was slowing down.
Using north as the positive direction for all calculations, determine:
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a.
b.
c.
a. | ||
b. Using
c. Using
Plane A is flying due north at 300 kmh
Calculate the velocity of plane B as measured by the pilots on plane B? (3 marks)
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Let north be the positive direction and south be the negative direction.
A hot-air balloon is travelling at a constant upwards velocity of 15 ms
A passenger on the hot-air balloon decides to time how long it takes a pen to hit the ground when dropped from a height of 50 m.
Ignoring air resistance, determine how long it will take the pen to hit the ground. (4 marks)
Downwards
Time for the pen to fall = 5.07 seconds
The network below shows the one-way paths between the entrance,
The vertices represent the intersections of the one-way paths.
The number on each edge is the maximum number of children who are allowed to travel along that path per minute.
The minimum cut of the network is drawn, showing the maximum flow capacity of the maze is 23 children per minute.
One path in the maze is to be changed.
Determine the changes in the maximum flow capacity of the network in each of the following changes
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i.
ii.
iii.
i.
ii.
iii.
The network below shows the one-way paths between the entrance,
The vertices represent the intersections of the one-way paths.
The number on each edge is the maximum number of children who are allowed to travel along that path per minute.
Cuts on this network are used to consider the possible flow of children through the maze.
Determine the capacity of the minimum cut of this network. (2 marks)
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The network below shows the one-way paths between the entrance,
The vertices represent the intersections of the one-way paths.
The number on each edge is the maximum number of children who are allowed to travel along that path per minute.
Question 39
Cuts on this network are used to consider the possible flow of children through the maze. The capacity of the minimum cut would be
Question 40
One path in the maze is to be changed.
Which one of these five changes would lead to the largest increase in flow from entrance to exit?
The adjacency matrix below represents a planar graph with five vertices.
The number of faces on the planar graph is
Four employees, Anthea, Bob, Cho and Dario, are each assigned a different duty by their manager.
The time taken for each employee to complete duties 1,2,3 and 4, in minutes, is shown in the table below
The manager allocates the duties so as to minimise the total time taken to complete the four duties.
The minimum total time taken to complete the four duties, in minutes, is
For one particular week in a school year, students at Phyllis Island Primary School can spend their lunch break at the playground
Students stay at the same location for the entire lunch break.
The transition diagram below shows the proportion of students who change location from one day to the next.
The transition diagram is incomplete.
On the Monday, 150 students spent their lunch break at the playground, 50 students spent it at the basketball courts, 220 students spent it at the oval, and 40 students spent it in the library.
Of the students expected to spend their lunch break on the oval on the Wednesday, the percentage of these students who also spent their lunch break on the oval on Tuesday is closest to
A species of bird has a life span of three years.
The females in this species do not reproduce in their first year but produce an average of four female offspring in their second year, and three in their third year.
The Leslie matrix,
The element in the second row, first column states that on average 20% of this population will
How many of the following statements are true?
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i.
ii.
i.
ii.
Complete the table below, describing the reactivity characteristics of the three metals listed. (3 marks)
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Metals such as Lead, Copper, Mercury and Silver do not react with dilute acids but will react with the same acids at higher concentration levels.
Explain why this occurs with reference to first ionisation energy. (3 marks)
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→ First ionsiation energy refers to the energy required to remove a valence electron from a metal.
→ Metals react in their ionised state and the less energy that is required to reach this state, the more reactive the metal.
→ Lead, Copper, Mercury and Silver require more energy to remove their outer valence electrons and consequently are only reactive in the presence of stronger oxidising agents.
→ Concentrated acids have more oxidising ability than their dilute counterparts and can react with these metals.
→ First ionsiation energy refers to the energy required to remove a valence electron from a metal.
→ Metals react in their ionised state and the less energy that is required to reach this state, the more reactive the metal.
→ Lead, Copper, Mercury and Silver require more energy to remove their outer valence electrons and consequently are only reactive in the presence of stronger oxidising agents.
→ Concentrated acids have more oxidising ability than their dilute counterparts and can react with these metals.
In a laboratory, students reacted aluminium with water to produce an oxide and hydrogen gas.
Which of the following equations correctly represents this reaction.
→ Aluminium is not reactive enough to form an oxide with liquid water over a short period. For this to occur additional energy needs to be input (eliminate B).
→ This can however be achieved by reacting the aluminium with steam, which has more energy than water.
→ Option D provides the only balanced equation of the remaining options.
Two moles of butane
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i.
ii.
i. Complete combustion equation:
→ Two moles of butane require 10 moles of oxygen to fully combust.
→
→ Oxygen is limiting reagent and butane will undergo incomplete combustion according to the following balanced equation:
ii. Using the equation in part (i), 2 moles of
The following recurrence relation models the value,
The value of
Timmy took out a reducing balance loan of $500 000, with interest calculated monthly.
The balance of the loan, in dollars, after
A final repayment that will fully repay the loan to the nearest cent is
For taxation purposes, Audrey depreciates the value of her $3000 computer over a four-year period. At the end of the four years, the value of the computer is $600.
Question 20
If Audrey uses flat rate depreciation, the depreciation rate, per annum is
Question 21
If Audrey uses reducing balance depreciation, the depreciation rate, per annum is closest to
The number of visitors each month to a zoo is seasonal.
To correct the number of visitors in January for seasonality, the actual number of visitors, to the nearest percent, is increased by 35%.
The seasonal index for that month is closest to
The number of visitors to a public library each day for 10 consecutive days was recorded.
These results are shown in the table below.
The eight-mean smoothed number of visitors with centring for day number 6 is
The following graph shows a selection of winning times, in seconds, for the women's 800 m track event from various athletic events worldwide. The graph shows one winning time for each calendar year from 2000 to 2022.
Question 13
The time series is smoothed using seven-median smoothing.
The smoothed value for the winning time in 2006, in seconds, is closest to
Question 14
The median winning time, in seconds, for all the calendar years from 2000 to 2022 is closest to
A least squares line can be used to model the birth rate (children per 1000 population) in a country from the average daily food energy intake (megajoules) in that country.
When a least squares line is fitted to data from a selection of countries it is found that:
The slope of this least squares line is closest to
A teacher analysed the class marks of 15 students who sat two tests.
The test 1 mark and test 2 mark, all whole number values, are shown in the scatterplot below.
A least squares line has been fitted to the scatterplot.
Question 7
The equation of the least squares line is closest to
Question 8
The least squares line shows the predicted test 2 mark for each student based on their test 1 mark.
The number of students whose actual test 2 mark was within two marks of that predicted by the line is
The heights of a group of Year 8 students have a mean of $163.56 cm and a standard deviation of $8.14 cm.
One student's height has a standardised
This student's height, in centimetres, is closest to
In the system diagram below, a 5-kilogram mass and masses
Using a vector diagram, calculate the masses of both
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Using the sin rule both
Outline and explain the process by which ferromagnetic materials can become magnetised using a bar magnet. (3 marks)
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→ A ferromagnetic material contains many free electrons due to its metallic bonding.
→ Each electron has its own magnetic domain but due to the electrons spinning in opposite directions, the domains cancel each other out.
→ Using a bar magnet, stroke the ferromagnetic material in one direction.
→ This causes the electrons to spin in the same direction, hence all of their domains line up.
→ The cumulative effect of all the small magnetic domains creates a large magnetic field, turning the ferromagnetic material into a magnet.
→ A ferromagnetic material contains many free electrons due to its metallic bonding.
→ Each electron has its own magnetic domain but due to the electrons spinning in opposite directions, the domains cancel each other out.
→ Using a bar magnet, stroke the ferromagnetic material in one direction.
→ This causes the electrons to spin in the same direction, hence all of their domains line up.
→ The cumulative effect of all the small magnetic domains creates a large magnetic field, turning the ferromagnetic material into a magnet.
A wire with a current of
If the current through the wire is halved and the distance
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Two long, straight current-carrying wires,
Figure 2b shows the wires as viewed from above.
On Figure 2b, sketch the magnetic field around the wires, showing the direction of the magnetic field. Use at least five field lines. (3 marks)
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→ Use the right-hand grip rule to determine the directions of the magnetic fields surrounding the currents, remembering that an
→ As the distance from the wire increases the field strength decreases according to the inverse square law and therefore does not decrease at a linear rate (as seen in the diagram by the greater distances between field lines the further from the wires).
Some physics students are conducting an experiment investigating both electrostatic and gravitational forces. They suspend two equally charged balls, each of mass 4.0 g, from light, non-conducting strings suspended from a low ceiling.
The charged balls repel each other with the strings at an angle of 60°, as shown in Figure 1.
There are three forces acting on each ball:
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a.
b. System is in an equilibrium state:
→ The sum of the forces must add to zero as seen in the triangle below.
→
c. Using the same triangle as part (b):
a.
b. System is in an equilibrium state:
→ The sum of the forces must add to zero as seen in the triangle below.
→
c. Using the same triangle as part (b):
A ray of monochromatic light is incident on a triangular glass prism with a refractive index of 1.52 . The ray is perpendicular to the side
The ray of light travels through the glass prism before reaching side
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a. 41°
b. As the angle of incidence 45° is greater than the critical angle 41°, the total internal reflection will occur on side
a. | ||
b. Total internal reflection:
→ The angle of incidence 45° is greater than the critical angle 41°.
→ Therefore, total internal reflection will occur on side
A guitar string of length 0.75 m and fixed at both ends is plucked and a standing wave is produced. The envelope of the standing wave is shown in Figure 13.
The speed of the wave along the string is 393 m s
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a. 262 Hz
b. Standing wave:
→ When waves encounter fixed ends, they reflect.
→ If the string’s length is a multiple of half the wavelength, the reflected wave combines with the original wave, resulting in interference that forms a standing wave pattern
a.
b. Standing wave:
→ When waves encounter fixed ends, they reflect.
→ If the string’s length is a multiple of half the wavelength, the reflected wave combines with the original wave, resulting in interference that forms a standing wave pattern
Maia is at a skatepark. She stands on her skateboard as it rolls in a straight line down a gentle slope at a constant speed of 3.0 m s
The combined mass of Maia and the skateboard is 65 kg.
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Near the bottom of the ramp, Maia takes hold of a large pole and comes to a complete rest while still standing on the skateboard. Maia and the skateboard now have no momentum or kinetic energy.
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a.
b. 55.5 N
c. Momentum:
→ Maia and the skateboards momentum was transferred into the pole and hence into the Earth. Due to the Earth’s very large mass, the effect on its velocity is negligible.
Kinetic energy:
→ The kinetic energy of Maia and the skateboard would have been transformed into heat energy between the contact of Maia and the pole and/or transferred into the work done by Maia’s muscles in slowing herself down.
a.
b. Total frictional forces:
→ Constant speed means that the force down the slope of the incline is equal to the sum of the frictional forces acting on Maia and the skateboard.
c. Momentum:
→ Maia and the skateboards momentum was transferred into the pole and hence into the Earth. Due to the Earth’s very large mass, the effect on its velocity is negligible.
Kinetic energy:
→ The kinetic energy of Maia and the skateboard would have been transformed into heat energy between the contact of Maia and the pole and/or transferred into the work done by Maia’s muscles in slowing herself down.
The diagram below shows the force versus time graph of the force on a tennis ball when it is hit by a tennis racquet. The tennis ball is stationary when the tennis racquet first comes into contact with the ball.
Which one of the following is closest to the impulse experienced by the tennis ball as it is hit by the tennis racquet?
→ The impulse is equal to the area under the curve
→ By splitting the areas into whole number of squares, there are about 10 squares.
→ Each square is
→ Hence the impulse experienced by the tennis ball
The diagram below shows two charges,
There is a force,
Which one of the following is closest to the magnitude of the force acting between the two charges if both
Standing waves are formed on a string of length 4.0 m that is fixed at both ends. The speed of the waves is 240 m s
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a. 30 Hz
b. 60 Hz
c. Standing waves:
→ Produced when a wave travels down a string and is reflected back on itself such that the superposition of the two waves produce an interference pattern to form a standing wave.
→ The two waves must be travelling in opposite directions with the same frequency, wavelength and amplitude.
a. Lowest frequency resonance:
→ Occurs at the maximum wavelength. The maximum wavelength is 8 metres since the half wavelength is the length of the string (4m).
b. When
c. Standing waves:
→ Produced when a wave travels down a string and is reflected back on itself such that the superposition of the two waves produce an interference pattern to form a standing wave.
→ The two waves must be travelling in opposite directions with the same frequency, wavelength and amplitude.
The enthalpies of formation for a number of chemical reactions are as follows:
Calculate the enthalpy change for the fermentation of glucose (reaction below) using the enthalpies of formation above.
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a. → The Neolithic revolution refers to the beginning of agriculture
→ It occurred about 10 000 years ago and includes the first instances of cultivating crops and domesticating animals.
b. Answers could include two of the following:
→ The Neolithic revolution heavily influenced the evolution of the human race, as well as the impacted ecosystems and related flora and fauna.
→ One immediate impact was an increase in human populations. The beginning of agriculture displaced a hunter gatherer lifestyle for many populations, providing an abundance of available food and leading to the first instances of villages and towns.
→ Another impact is soil erosion. The removal of deep-rooted vegetation for crops depleted the environment for many organisms and caused major disruption of the ecosystem. This process leads directly to deforestation which remains a major problem in modern agriculture.
a. → The Neolithic revolution refers to the beginning of agriculture
→ It occurred about 10 000 years ago and includes the first instances of cultivating crops and domesticating animals.
b. Answers could include two of the following:
→ The Neolithic revolution heavily influenced the evolution of the human race, as well as the impacted ecosystems and related flora and fauna.
→ One immediate impact was an increase in human populations. The beginning of agriculture displaced a hunter gatherer lifestyle for many populations, providing an abundance of available food and leading to the first instances of villages and towns.
→ Another impact is soil erosion. The removal of deep-rooted vegetation for crops depleted the environment for many organisms and caused major disruption of the ecosystem. This process leads directly to deforestation which remains a major problem in modern agriculture.
Three unknown metals are reacted with dilute
You are told that the metals in question are Magnesium, Platinum and Zinc.
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i. → The metals
→ Magnesium is the most reactive as it is an alkali earth metal (Metal
→ Zinc and Platinum are both less reactive than magnesium. Zinc however exists higher on the reactivity series of metals than Platinum which is the least reactive of the three metals.
→ Therefore, metal
ii. → A single displacement reaction.
iii. Include one of the following:
i. → The metals
→ Magnesium is the most reactive as it is an alkali earth metal (Metal
→ Zinc and Platinum are both less reactive than magnesium. Zinc however exists higher on the reactivity series of metals than Platinum which is the least reactive of the three metals.
→ Therefore, metal
ii. → A single displacement reaction.
iii. Include one of the following:
Climate change is altering the Earth’s habitats and ecosystems, putting many species at risk of global population reductions or extinction.
Justify this statement, giving real world examples of climate change. (5 marks)
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→ Climate change is altering organisms environments across the globe, causing drastic population reductions and even extinctions of entire species.
→ One reason for sudden changes in populations is the increase in devastating and extreme weather events because of climate change. Storms, fires and extended droughts result in devastating death tolls in both plant and animal communities, eliminating individuals and drastically changing the gene pool.
→ Climate change also produces more incremental impacts on the environment. Steadily increasing temperatures and changes in precipitation patterns are two examples. Many organisms cannot adapt to these changes, causing depopulation and extinctions.
→ One example of a changing temperature on the environment is ocean acidification. Rising temperatures have a drastic effect coral health and its associated marine life. Acidification of the water also makes it difficult for many crustaceans to form hard shells.
→ The ecosystems themselves also play a large role in climate change, as plants act as a climate regulator due to their ability to store carbon. However, as climate change grows at an exponential rate, plants cannot adapt quickly enough and die out. This results in less carbon storage and a dangerous negative feedback loop.
→ It is therefore accurate to state that climate change alters ecosystems worldwide causing large population declines of species and eventually climate extinctions for some.
→ Climate change is altering organisms environments across the globe, causing drastic population reductions and even extinctions of entire species.
→ One reason for sudden changes in populations is the increase in devastating and extreme weather events because of climate change. Storms, fires and extended droughts result in devastating death tolls in both plant and animal communities, eliminating individuals and drastically changing the gene pool.
→ Climate change also produces more incremental impacts on the environment. Steadily increasing temperatures and changes in precipitation patterns are two examples. Many organisms cannot adapt to these changes, causing depopulation and extinctions.
→ One example of a changing temperature on the environment is ocean acidification. Rising temperatures have a drastic effect coral health and its associated marine life. Acidification of the water also makes it difficult for many crustaceans to form hard shells.
→ The ecosystems themselves also play a large role in climate change, as plants act as a climate regulator due to their ability to store carbon. However, as climate change grows at an exponential rate, plants cannot adapt quickly enough and die out. This results in less carbon storage and a dangerous negative feedback loop.
→ It is therefore accurate to state that climate change alters ecosystems worldwide causing large population declines of species and eventually climate extinctions for some.
The landing gear on an aircraft uses a hydraulic braking system. A force of 60 N is applied at the master cylinder with a piston diameter of 12 mm.
What is the force at the brake calliper with a piston diameter of 42 mm ?
→ Pressure is the same in both master cylinder and brake calliper
→ Convert units:
→ Using
A portion of a roller coaster wheel sub-assembly is shown.
An exploded pictorial of the wheel sub-assembly is shown.
Complete an assembled sectioned front view of the wheel sub-assembly at scale 1: 2. Apply AS 1100 drawing standards. Do NOT add dimensions. (6 marks)
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The enthalpies of reaction of a number of chemical reactions are as follows:
Reaction 1:
Reaction 2:
Reaction 3:
Calculate the enthalpy change for the reaction below, stating whether the reaction is exothermic or endothermic:
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→ Reverse equation 1 to make
→ Add a multiplier to Reaction 2 as this will allow the
→ Add the equations and their
|
||
|
→ The reaction is endothermic.
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a. Grass, carrots and grain.
b. Carnivore: Owl or fox
Herbivore: Bird
c. Extinction of the grasshopper effects:
→ Will result in a greater availability of the grass and grain they (previously) ate.
→ Subsequently, there will be less competition for food among the other species which also eat grass and grain. These species will thrive and an increase in the bird, mouse and rabbit populations would be expected.
→ The grasshoppers’ extinction will also cause its consumers, the bird and the owl, to have to find other food sources.
→ Population fluctuations of birds and owls would be expected as they adapt to new hunting or grazing habits to replace their lost food source.
→ The complexity of nature in such extinction events can be seen particularly on birds who benefit from more grain availability but lose grasshoppers as a direct food source.
a. Grass, carrots and grain.
b. Carnivore: Owl or fox
Herbivore: Bird
c. Extinction of the grasshopper effects:
→ Will result in a greater availability of the grass and grain they (previously) ate.
→ Subsequently, there will be less competition for food among the other species which also eat grass and grain. These species will thrive and an increase in the bird, mouse and rabbit populations would be expected.
→ The grasshoppers’ extinction will also cause its consumers, the bird and the owl, to have to find other food sources.
→ Population fluctuations of birds and owls would be expected as they adapt to new hunting or grazing habits to replace their lost food source.
→ The complexity of nature in such extinction events can be seen particularly on birds who benefit from more grain availability but lose grasshoppers as a direct food source.
Which of the following is a recognised impact test?
→ The recognised impact test among the options provided is option C, Notch.
→ The Brinell test measure material hardness, Erichsen test measures the properties of metals (including hardness and wear) while the punch test looks at material behaviour under stress.
Why did steel replace cast iron in bridges built after 1850 ?
→ Steel is stronger, more ductile, and has a higher tensile strength compared to cast iron, allowing for the construction of larger and more durable structures.
→ Cast iron generally has greater compressive strength than steel (eliminate D).