Which of the following trends explains why metals become more reactive as you move down a group in the periodic table?
- Increasing ionisation energy
- Increasing electronegativity
- Decreasing atomic radius
- Decreasing ionisation energy
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Which of the following trends explains why metals become more reactive as you move down a group in the periodic table?
\(D\)
\(\Rightarrow D\)
The curves `y=(x-1)^2` and `y=5-x^2` intersect at two points, as shown in the diagram.
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a. `x=2\ \text{and}\ -1`
b. `9\ \text{units}^2`
a. `y=(x-1)^2, \ y=5-x^2`
\(\text{Intersection occurs when:}\)
| `(x-1)^2` | `=5-x^2` | |
| `x^2-2x+1` | `=5-x^2` | |
| `2x^2-2x-4` | `=0` | |
| `2(x-2)(x+1)` | `=0` |
`x=2\ \text{and}\ -1`
| b. | `\text{Area}` | `= \int_{-1}^{2} (5-x^2)-(x-1)^2\ dx` |
| `=\int_{-1}^{2} 5-x^2-x^2+2x-1\ dx` | ||
| `=\int_{-1}^{2}4-2x^2+2x\ dx` | ||
| `=[4x-\frac{2}{3}x^3+x^2]_{-1}^{2}` | ||
| `=[(8-\frac{16}{3}+4)-(-4+\frac{2}{3}+1)]` | ||
| `=\frac{20}{3}-(-\frac{7}{3})` | ||
| `=9\ \text{u}^2` |
Consider the function shown.
Which of the following could be the equation of this function?
\(C\)
\(\text {Gradient is negative (top left } \rightarrow \text { bottom right)}\)
\(y \text{-intercept = 3 (only positive option)}\)
\(\Rightarrow C\)
\begin{array} {|c|c|}
\hline
\rule{0pt}{2.5ex} \text{Standard potentials} \rule[-1ex]{0pt}{0pt} & \qquad E^{\circ}\ \text{V} \qquad\\
\hline
\rule{0pt}{2.5ex} \ce{Fe(s)/Fe^{2+}} \rule[-1ex]{0pt}{0pt} & -0.44 \\
\hline
\rule{0pt}{2.5ex} \ce{Ag(s)/Ag^{+}} \rule[-1ex]{0pt}{0pt} & 0.8 \\
\hline
\rule{0pt}{2.5ex} \ce{Zn(s)/Zn^{2+}} \rule[-1ex]{0pt}{0pt} & -0.76 \\
\hline
\rule{0pt}{2.5ex} \ce{Ni(s)/Ni^{2+}} \rule[-1ex]{0pt}{0pt} & -0.24 \\
\hline
\end{array}
Using the table above which would be the correct order of reactivity if the metals are ranked in order of decreasing electrochemical reactivity?
\(A\)
\(\Rightarrow A\)
A student set up two half-cells: one with an aluminium nitrate solution and an aluminium metal electrode, and the other with silver nitrate solution and a silver metal electrode. The two solutions were connected by a salt bridge soaked in potassium nitrate, and the electrodes were linked to a volt-meter using electrical wires.
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\begin{array} {|c|c|}
\hline
\rule{0pt}{2.5ex} \text{anode half equation} \rule[-1ex]{0pt}{0pt} & \qquad \qquad\qquad \qquad \qquad \\
\hline
\rule{0pt}{2.5ex} \text{cathode half equation} \rule[-1ex]{0pt}{0pt} & \\
\hline
\rule{0pt}{2.5ex} \text{net ionic equation} \rule[-1ex]{0pt}{0pt} & \\
\hline
\end{array}
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b.
\begin{array} {|c|c|}
\hline
\rule{0pt}{2.5ex} \text{anode half equation} \rule[-1ex]{0pt}{0pt} & \ce{Al(s) -> Al^{3+}(aq) + 3e^-}\\
\hline
\rule{0pt}{2.5ex} \text{cathode half equation} \rule[-1ex]{0pt}{0pt} & \ce{Ag+(aq) + e^- -> Ag(s)} \\
\hline
\rule{0pt}{2.5ex} \text{net ionic equation} \rule[-1ex]{0pt}{0pt} & \ce{Al(s) + Ag+(aq) -> Al^{3+}(aq) + Ag(s)} \\
\hline
\end{array}
c. \(E^{\circ}_{\text{cell}}=E^{\circ}_{\text{cathode}}-E^{\circ}_{\text{anode}}=0.8-(-1.68)=2.48\ \text{V}\)
b.
\begin{array} {|c|c|}
\hline
\rule{0pt}{2.5ex} \text{anode half equation} \rule[-1ex]{0pt}{0pt} & \ce{Al(s) -> Al^{3+}(aq) + 3e^-}\\
\hline
\rule{0pt}{2.5ex} \text{cathode half equation} \rule[-1ex]{0pt}{0pt} & \ce{Ag+(aq) + e^- -> Ag(s)} \\
\hline
\rule{0pt}{2.5ex} \text{net ionic equation} \rule[-1ex]{0pt}{0pt} & \ce{Al(s) + Ag+(aq) -> Al^{3+}(aq) + Ag(s)} \\
\hline
\end{array}
c. \(E^{\circ}_{\text{cell}}=E^{\circ}_{\text{cathode}}-E^{\circ}_{\text{anode}}=0.8-(-1.68)=2.48\ \text{V}\)
A student conducted an experiment to measure the voltage generated by using various combinations of metals in an electrolyte solution.
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\begin{array} {|c|c|c|c|}
\hline
\rule{0pt}{2.5ex} \textbf{Experiment} \rule[-1ex]{0pt}{0pt} & \textbf{Half cell A} & \textbf{Half cell B} & \textbf{Cell Potential (V)}\\
\hline
\rule{0pt}{2.5ex} \textbf{1} \rule[-1ex]{0pt}{0pt} & \ce{Zn(s) | Zn^{2+}(aq)} & \ce{Pb(s) | Pb^{2+}(aq)} & \\
\hline
\rule{0pt}{2.5ex} \textbf{2} \rule[-1ex]{0pt}{0pt} & \ce{Cu(s) | Cu^{2+}(aq)} & \ce{Pb(s) | Pb^{2+}(aq)} & \\
\hline
\end{array}
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a. Cell potential of Experiment 1:
\(\ce{Zn(s) -> Zn^{2+} + 2e^-} \quad V=0.76\ \text{V}\)
\(\ce{Pb^{2+} + 2e^- -> Pb(s)} \quad V=-0.13\ \text{V}\)
\(E^{\circ}_{\text{cell}}=0.76 + -0.13 =0.63\ \text{V}\)
Cell potential of Experiment 2:
\(\ce{Pb(s) -> Pb^{2+} + 2e^-} \quad V=0.13\ \text{V}\)
\(\ce{Cu^{2+} + 2e^- -> Cu(s)} \quad V=0.34\ \text{V}\)
\(E^{\circ}_{\text{cell}}=0.13 + 0.34 =0.47\ \text{V}\)
b. Zinc electrode is the anode.
c. \(\ce{Pb(s) + Cu^{2+}(aq) -> Pb^{2+}(aq) + Cu(s)}\)
a. Cell potential of experiment 1:
\(\ce{Zn(s) -> Zn^{2+} + 2e^-} \quad V=0.76\ \text{V}\)
\(\ce{Pb^{2+} + 2e^- -> Pb(s)} \quad V=-0.13\ \text{V}\)
\(E^{\circ}_{\text{cell}}=0.76 + -0.13 =0.63\ \text{V}\)
Cell potential of experiment 2:
\(\ce{Pb(s) -> Pb^{2+} + 2e^-} \quad V=0.13\ \text{V}\)
\(\ce{Cu^{2+} + 2e^- -> Cu(s)} \quad V=0.34\ \text{V}\)
\(E^{\circ}_{\text{cell}}=0.13 + 0.34 =0.47\ \text{V}\)
b. Zinc electrode is the anode.
c. \(\ce{Pb(s) + Cu^{2+}(aq) -> Pb^{2+}(aq) + Cu(s)}\)
For which pair of substances will a displacement reaction occur?
\(A\)
\(\Rightarrow A\)
Identify the compound in which chromium has an oxidation state of 6.
\(C\)
Let \(x\) be the oxidation state of chromium in each of the following calculations.
\(\ce{CrCl3}\) → \(x+3(-1)=0\ \ \Rightarrow \ \ x=3\)
\(\ce{Cr2O3}\) → \(2x+3(-2)=0\ \ \Rightarrow \ \ x=3\)
\(\ce{K2Cr2O7}\) → \(2(1)+ 2x+7(-2)=0\ \ \Rightarrow \ \ x=6\)
\(\ce{Cr(OH)3}\) → \(x+3(-1)=0\ \ \Rightarrow \ \ x=3\)
\(\Rightarrow C\)
A galvanic cell was created as seen below:
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a. The electrons will run from the nickel electrode to the copper electrode.
b. Nickel electrode \(\Rightarrow\) is the anode (undergoes oxidation).
Copper electrode \(\Rightarrow\) cathode (undergoes reduction).
c. The nitrate ions in the salt bridge will flow to the nickel solution.
a. The electrons will run from the nickel electrode to the copper electrode.
b. Nickel electrode \(\Rightarrow\) is the anode (undergoes oxidation).
Copper electrode \(\Rightarrow\) cathode (undergoes reduction).
c. The nitrate ions in the salt bridge will flow to the nickel solution.
Which statement is correct for the following reaction?
\(\ce{Zn(s) + Cu^{2+}(aq) -> Zn^{2+}(aq) + Cu(s)}\)
\(B\)
\(\Rightarrow B\)
A 3000 hectare koala sanctuary was created in 1980 and the koala population over the next 35 years was monitored and the data graphed below.
Identify and explain the ecological significance of the parts of the graph labelled A, B and C. (5 marks)
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Curve at point A:
Curve at point B:
Curve at point C:
Curve at point A:
Curve at point B:
Curve at point C:
In the diagram of a partial cross-section of a vascular plant stem shown below, identify the labeled structure representing the cells responsible for translocation.
\(B\)
\(\Rightarrow B\)
A galvanic cell has been set up as illustrated in the diagram below.
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a. \(\ce{Fe(s) -> Fe^{2+} + 2e^-}\)
b. As the reaction progresses:
c. \(0.137\ \text{mol L}^{-1}\)
| a. | \(E^{\circ}_{\text{cell}}\) | \(=E^{\circ}_{\text{cathode}}-E^{\circ}_{\text{anode}}\) |
| \(0.78\) | \(=0.34-E^{\circ}_{\text{anode}}\) | |
| \(E^{\circ}_{\text{anode}}\) | \(=0.34-0.78\) | |
| \(E^{\circ}_{\text{anode}}\) | \(=-0.44\) | |
b. As the reaction progresses:
c. Moles of solid copper formed on electrode: \(\dfrac{m}{MM}=\dfrac{0.175}{63.55}=2.36 \times 10^{-3}\ \text{mol}\)
Moles of copper taken out of solution: \(2.36 \times 10^{-3}\ \text{mol}\)
Moles of copper remaining in solution: \((0.15 \times 0.18)-2.36 \times 10^{-3}= 0.0246\ \text{mol}\)
Final concentration: \(c=\dfrac{n}{V}=\dfrac{0.0246}{0.18}=0.137\ \text{mol L}^{-1}\)
Examine the diagram provided, which depicts the biological relationships within an ecosystem.
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a. Food webs vs food chains:
b. Second trophic level \(\Rightarrow\) first order consumer
Zebra or Impala
c. Ecological consequences:
a. Food webs vs food chains:
b. Second trophic level \(\Rightarrow\) first order consumer
Zebra or Impala
c. Ecological consequences:
Describe the concept of an ecological niche and its significance within an ecosystem's structure. (2 marks)
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Which of the following is an example of a parasitic relationship?
\(B\)
\(\Rightarrow B\)
Describe the differences between mutualistic and parasitic symbiotic relationships in ecosystems. In your answer, provide one specific example of each type of relationship from nature. (3 marks)
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Consider a grassland ecosystem with a population of rabbits, foxes, and various grass species.
a. Predation occurs when foxes hunt and eat rabbits.
b. Competition among rabbits could result from (choose two):
c. Removing foxes:
a. Predation occurs when foxes hunt and eat rabbits.
b. Competition among rabbits could result from (choose two):
c. Removing foxes:
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a. Abiotic factor
b. Soil pH:
c. Plants alter soil pH (choose 1):
a. Abiotic factor
b. Soil pH:
c. Plants alter soil pH (choose 1):
Explain the concept of a trophic relationship and evaluate its significance within an ecosystem's functioning. (3 marks)
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Which of the following best describes the role of predictive models in managing future ecosystems?
\(D\)
\(\Rightarrow D\)
Human activities have significantly impacted species survival throughout history. Which of the following examples best demonstrates how understanding past human-induced extinctions can inform future ecosystem management?
\(C\)
\(\Rightarrow C\)
Indigenous land management practices are increasingly recognised for their effectiveness in ecosystem restoration.
Describe one specific case study where traditional knowledge has been applied to heal a damaged ecosystem in Australia. In your answer, explain the concept of 'Country' or 'Place' in this context and outline two specific restoration strategies used, highlighting their cultural significance. (5 marks)
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Case study 1: Pilliga forest in NSW (one example of many)
Case study 2: Restoration of the Gulgalda in Tasmania
Case study 1: Pilliga forest in NSW (one example of many)
Case study 2: Restoration of the Gulgalda in Tasmania
Agricultural intensification has led to widespread land degradation in many parts of the world.
Identify two major forms of land degradation resulting from agricultural practices. In your answer, describe a specific restoration technique used to address each form of degradation. (4 marks)
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Soil erosion:
Soil salinisation:
Soil erosion:
Soil salinisation:
Mining activities often leave significant impacts on ecosystems. Environmental scientists and ecologists work to develop and implement restoration practices to heal these damaged landscapes.
Describe two specific restoration practices commonly used in post-mining landscapes. In your answer, identify one challenge faced in the restoration process and how it might be overcome. (4 marks)
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Restoration practices (choose 2)
Restoration challenge/response:
Restoration practices (choose 2)
Restoration challenge/response:
A student set up a galvanic cell using two half-cells: \(\ce{Cu(s)/Cu^{2+}}\) and \(\ce{Zn(s)/Zn^{2+}}\). Assuming standard conditions, what is the maximum potential difference (emf) the student would expect to measure between the two half-cells?
\(C\)
\(\Rightarrow C\)
What is the oxidation state of sulfur in the sulfate ion, \(\ce{SO4^{2-}}\)?
\(C\)
| \(x +4(-2)\) | \(=-2\) | |
| \(x-8\) | \(=-2\) | |
| \(x\) | \(=6\) |
\(\Rightarrow C\)
In an era of rapid environmental change, scientists are developing sophisticated tools to anticipate shifts in biodiversity. Briefly explain two distinct models scientists use to predict future impacts on biodiversity. (2 marks)
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Answers could include two of the following:
Answers could include two of the following:
Our actions as a human species are inadvertently altering the evolutionary trajectories of countless organisms.
Explain two distinct mechanisms by which human activities exert selection pressures on other species. For each mechanism, provide a specific example of a species affected by this pressure. (4 marks)
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Answers could include two of the following.
Mechanism: urbanisation
Mechanism: pollution from fossil fuel burning
Mechanism: use of pesticides
Answers could include two of the following.
Mechanism: urbanisation
Mechanism: pollution from fossil fuel burning
Mechanism: use of pesticides
Describe two common indicators of a chemical change. Provide an example of each indicator. (3 marks)
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Other answers could include: the formation of a precipitate, change in temperature, light being produced.
Other answers could include: the formation of a precipitate, change in temperature, light being produced.
Human activities have become a powerful force in the natural world, often altering the course of evolution.
Explain the concept of human-induced selection pressures and in your answer, describe two specific examples where these pressures have led to species extinction. (3 marks)
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Extinction examples (choose two):
Extinction examples (choose two):
Ecosystems are dynamic, shaped not only by physical forces but also by the living organisms within them. Including a specific example, explain one biotic factor that has significantly impacted past ecosystems:
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a. Short timescale biotic factor: introduction of invasive species
b. Geological timescale biotic factor: evolution of land plants
a. Short timescale biotic factor: introduction of invasive species
b. Geological timescale biotic factor: evolution of land plants
Over geological timescales, our planet's ecosystems have undergone dramatic transformations. Name and briefly explain two abiotic factors that have played significant roles in driving these long-term changes in past ecosystems. (2 marks)
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A student tested how soluble silver salts are by reacting a 0.1 mol L\(^{-1}\) silver nitrate solution with 0.1 mol L\(^{-1}\) solutions of calcium hydroxide, calcium chloride, and calcium sulfate. The results are shown below:
\begin{array} {|l|l|}
\hline \ \ \ \ \ \text{Compound} & \ \ \ \ \ \text{Observation} \\
\hline \text{calcium hydroxide} & \text{No reaction} \\
\hline \text{calcium chloride} & \text{White precipitate} \\
\hline \text{calcium sulfate} & \text{No reaction} \\
\hline \end{array}
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a. \(\ce{CaCl2(aq) + 2AgNO3(aq) -> Ca(NO3)2(aq) + 2AgCl(s)}\)
b. The white precipitate is \(\ce{AgCl}\) → silver chloride.
a. \(\ce{CaCl2(aq) + 2AgNO3(aq) -> Ca(NO3)2(aq) + 2AgCl(s)}\)
b. The white precipitate is \(\ce{AgCl}\) → silver chloride.
Explain how the unique abiotic factors of the Australian continent have influenced the evolution of sclerophyll plants. In your answer, provide two specific adaptations. (4 marks)
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Analyse the evidence for the evolution of marsupials in Australia. In your answer, describe one piece of fossil evidence that supports the evolution of marsupials in Australia and provide one limitation of using fossil evidence to reconstruct evolutionary histories. (4 marks)
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The graph below shows the concentration of \(\ce{CO2}\) in the earth's atmosphere over the last 800 years.
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a. Data would be obtained by gas analysis within ice cores.
b. Graph shape over the past 800 years:
a. Data would be obtained by gas analysis within ice cores.
b. Graph shape over the past 800 years:
Which of the following statements about radiometric dating is correct?
\(B\)
Consider each statement.
\(\Rightarrow B\)
Geologists often say that rocks are pages in Earth's history book.
Explain how scientists use paleontological and geological evidence from rock structures and formations to reconstruct past ecosystems and their changes over time. Include a specific example in your answer. (3 marks)
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Describe two ways in which ice core data provides evidence of past changes in ecosystems. (2 marks)
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Answers could include two of the following:
Answers could include two of the following:
Aboriginal rock paintings provide valuable insights into Australia's past ecosystems and the changes they've undergone over time.
Explain why Aboriginal rock paintings are considered a valid source of ecological information and how it complements other forms of paleontological data in understanding ecosystem changes. (4 marks)
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Describe two examples of paleontological evidence from Australia that provide insights into past changes in ecosystems. (4 marks)
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Example 1: Megafauna fossils in the Naracoorte Caves, South Australia
Example 2: Plant microfossils from the Atherton Tablelands, Qld
Example 1: Megafauna fossils in the Naracoorte Caves, South Australia
Example 2: Plant microfossils from the Atherton Tablelands, Qld
Absolute dating techniques provide crucial information about the age of fossils and rocks, but different methods are suitable for different time periods.
Describe two absolute dating methods used by scientists, each appropriate for a different time scale. (4 marks)
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Carbon-14 dating:
Potassium-40 dating:
Carbon-14 dating:
Potassium-40 dating:
Paleontologists use various methods to determine the age of fossils, providing crucial information about Earth's history and the evolution of life.
Describe two techniques that can be used to date fossils. In your answer, discuss one advantage and one limitation of each method. (4 marks)
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Stratigraphy:
Radiocarbon dating:
Stratigraphy:
Radiocarbon dating:
Consider the following:
Which combination correctly identifies examples of comparative embryology and biogeography?
\(A\)
\(\Rightarrow A\)
Which type of evidence for evolution is demonstrated by the similarity in DNA sequences of the FOXP2 gene in humans and chimpanzees?
\(C\)
\(\Rightarrow C\)
Ginkgo biloba, often called a 'living fossil', is the only surviving species of the division Ginkgophyta. While native to China today, fossils of ginkgo-like plants have been found on every continent except Antarctica.
These fossils date back to the Permian period, over 270 million years ago. Ginkgo fossils have been discovered in locations as diverse as North America, Europe, and Australia.
Explain how this widespread fossil distribution of Ginkgo, compared to its limited native range today, supports the theory of evolution by natural selection. (4 marks)
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Comparative embryology provides compelling evidence for Darwin and Wallace's Theory of Evolution by Natural Selection.
Describe two examples of embryological similarities across different species and explain how these examples support the theory of evolution. (4 marks)
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Answers could include two of the following:
Gill slits
Tail bones
Pharyngeal arches
Answers could include two of the following:
Gill slits
Tail bones
Pharyngeal arches
On a remote island, a group of flightless birds called the Insulavis live peacefully.
These birds have small, stubby appendages where their wings should be. Despite never using these appendages for flight, every Insulavis is born with them.
Using your understanding of Darwin and Wallace's Theory of Evolution by Natural Selection, explain how the presence of these structures in Insulavis supports the theory of evolution. In your answer, provide a possible evolutionary scenario that could have led to the current state of Insulavis wings. (4 marks)
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Describe one type of biochemical evidence that provides strong support for Darwin and Wallace's Theory of Evolution by Natural Selection. (2 marks)
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Answers could include one of the following:
Oxygen transporting proteins
DNA
Answers could include one of the following:
Oxygen transporting proteins
DNA
How does the presence of a catalyst influence the rate of a chemical reaction? (2 marks)
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The fruits of the cycad Macrozamia, are known to be highly toxic for consumption.
Which of the following methods conducted by Indigenous peoples is most effective in removing toxins from this cycad?
\(C\)
\(\Rightarrow C\)
For centuries, Indigenous Australians have used chemical processes to detoxify certain foods. The seeds of the nardoo fern (Marsilea) were a traditional food source, but they contain harmful toxins. To safely consume the seeds, they were first ground into a paste and soaked in water for several days.
Soaking the nardoo seeds aids in detoxification by:
\(C\)
\(\Rightarrow C\)
"Natural selection is the architect of biodiversity."
Justify this statement. In your answer, describe how natural selection can lead to changes in a population and over time, increased biodiversity. Provide an example from the Australian ecosystems that demonstrates this relationship. (5 marks)
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a. Convergent evolution definition:
b. Key principles that lead to convergent evolution:
c. Australian fauna (example):
Non-Australian (example):
a. Convergent evolution definition:
b. Key principles that lead to convergent evolution:
c. Australian fauna (example):
Non-Australian (example):
Which of the following groups of organisms is the best example of divergent evolution?
\(B\)
\(\Rightarrow B\)
Which of the following pairs of organisms best demonstrates convergent evolution?
\(A\)
\(\Rightarrow A\)
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a. Difference between microevolution and macroevolution:
b. Answers could include one of the following examples.
Evolution of the platypus:
Evolution of the horse:
a. Difference between microevolution and macroevolution:
b. Answers could include one of the following examples.
Evolution of the platypus:
Evolution of the horse:
Which of the following scenarios best demonstrates a physiological adaptation rather than a structural or behavioural adaptation in an Australian organism?
\(D\)
\(\Rightarrow D\)
Many plants in hot climates exhibit leaf droop, where their leaves hang downwards during the hottest parts of the day.
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a. Behavioural adaptation.
b. This adaption is beneficial because:
a. Behavioural adaptation.
b. This adaption is beneficial because: