Products of an enzyme-controlled reaction can sometimes inhibit the enzyme that produced them.
Discuss how this process can be advantageous for cellular metabolism. (3 marks)
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Products of an enzyme-controlled reaction can sometimes inhibit the enzyme that produced them.
Discuss how this process can be advantageous for cellular metabolism. (3 marks)
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→ When products of an enzyme-controlled reaction inhibit the enzyme that produced them, it regulates the cell’s metabolism (in a process known as feedback).
→ This process prevents the accumulation of excess products, ensuring that resources like ATP and raw materials are used efficiently.
→ By controlling the enzyme activity, the cell can balance production according to its needs, conserving energy and maintaining metabolic stability.
→ When products of an enzyme-controlled reaction inhibit the enzyme that produced them, it regulates the cell’s metabolism (in a process known as feedback).
→ This process prevents the accumulation of excess products, ensuring that resources like ATP and raw materials are used efficiently.
→ By controlling the enzyme activity, the cell can balance production according to its needs, conserving energy and maintaining metabolic stability.
How do temperature and pH affect enzyme activity? In your answer, briefly explain how extreme conditions of each factor influence enzyme function. (4 marks)
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→ Temperature and pH significantly impact enzyme activity.
→ At high temperatures, enzymes can denature, losing their shape and functionality. At extreme heat, the active site can be destroyed or made inaccessible.
→ At low temperatures, enzyme activity slows down due to reduced molecular movement.
→ Certain enzymes have evolved to be most effective in specific pH environments (such as the acidity of the stomach) and are much less effective in more alkaline settings.
→ Extreme pH levels can alter the enzyme’s structure, affecting the active site’s ability to bind with substrates.
→ Optimal enzyme activity occurs within specific temperature and pH ranges for each enzyme.
→ Temperature and pH significantly impact enzyme activity.
→ At high temperatures, enzymes can denature, losing their shape and functionality. At extreme heat, the active site can be destroyed or made inaccessible.
→ At low temperatures, enzyme activity slows down due to reduced molecular movement.
→ Certain enzymes have evolved to be most effective in specific pH environments (such as the acidity of the stomach) and are much less effective in more alkaline settings.
→ Extreme pH levels can alter the enzyme’s structure, affecting the active site’s ability to bind with substrates.
→ Optimal enzyme activity occurs within specific temperature and pH ranges for each enzyme.
Compare the movement of a lipid-soluble substance and water across the cell membrane.
In your answer, explain how the structure of the membrane affects the transport of these molecules. (2 marks)
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→ Lipid-soluble substances can pass directly through the phospholipid bilayer by simple diffusion because the cell membrane contains lipids.
→ In contrast, water is unable to penetrate the cell through the phospholipid bilayer.
→ Instead, water molecules must pass through special protein channels (pores) in the cell membrane.
→ Lipid-soluble substances can pass directly through the phospholipid bilayer by simple diffusion because the cell membrane contains lipids.
→ In contrast, water is unable to penetrate the cell through the phospholipid bilayer.
→ Instead, water molecules must pass through special protein channels (pores) in the cell membrane.
In active transport, how does the cell maintain a steep concentration gradient across the membrane?
\(B\)
→ Active transport requires energy (ATP) to move ions or molecules against their concentration gradient, often with the help of carrier proteins.
→ This process helps cells maintain steep concentration gradients essential for functions like nerve impulse transmission and muscle contraction.
\(\Rightarrow B\)
Explain how lysosomes contribute to the maintenance of normally functioning cells, and describe what happens when the function of lysosomes is impaired. (2 marks)
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→ Lysosomes maintain cellular homeostasis by breaking down waste materials, damaged organelles, and cellular debris using enzymes.
→ This prevents the accumulation of harmful substances.
→ When lysosomal function is impaired, waste products and damaged components build up, leading to cellular dysfunction and potentially contributing to diseases that impair cellular efficiency and overall health.
→ Lysosomes maintain cellular homeostasis by breaking down waste materials, damaged organelles, and cellular debris using enzymes.
→ This prevents the accumulation of harmful substances.
→ When lysosomal function is impaired, waste products and damaged components build up, leading to cellular dysfunction and potentially contributing to diseases that impair cellular efficiency and overall health.
Which of the following correctly describes the roles of lysosomes and the Golgi apparatus?
\(C\)
→ Lysosomes contain digestive enzymes that break down cellular waste and debris.
→ Golgi apparatus is responsible for modifying, sorting, and packaging proteins for secretion or use within the cell.
\(\Rightarrow C\)
According to the fluid mosaic model of the cell membrane
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a. The phospholipid bilayer:
→ Consists of two layers of phospholipids.
→ One layer involves hydrophilic (water-attracting) heads facing outward toward the water-based environment while the opposite layer has hydrophobic (water-repelling) tails facing inward, away from water.
b. Proteins:
→ are embedded in the double phospholid layer and play a role in the cell structure and communication.
a. The phospholipid bilayer:
→ Consists of two layers of phospholipids.
→ One layer involves hydrophilic (water-attracting) heads facing outward toward the water-based environment while the opposite layer has hydrophobic (water-repelling) tails facing inward, away from water.
b. Proteins:
→ are embedded in the double phospholid layer and play a role in the cell structure and communication.
A student wanted to investigate the effect of two different endonucleases (restriction enzymes) on a linear DNA fragment. The student used three tubes containing a buffered solution of linear DNA fragments, each fragment being 9500 base pairs in length. Two different endonucleases were available: BamHI and HindIII. The student followed the steps below. After 45 minutes the student obtained the results shown below Analyse the results of the experiment performed by the student. (5 marks) --- 10 WORK AREA LINES (style=lined) --- Answers could include 5 of the following: → Smaller DNA fragments tend to migrate further during gel electrophoresis → A standard or marker is used as a point of comparison and reference to → The restriction enzyme BamH1 cuts the DNA molecule at a single location, → The restriction enzyme HindIII cuts the DNA molecule at two distinct → When the DNA is cut with the HindIII enzyme, it results in the largest and → The DNA fragments generated by the BamH1 enzyme are 4000 bp and → When the DNA is digested with both BamH1 and HindIII enzymes, a total Answers could include 5 of the following: → Smaller DNA fragments tend to migrate further during gel electrophoresis → A standard or marker is used as a point of comparison and reference to → The restriction enzyme BamH1 cuts the DNA molecule at a single location, → The restriction enzyme HindIII cuts the DNA molecule at two distinct → When the DNA is cut with the HindIII enzyme, it results in the largest and → The DNA fragments generated by the BamH1 enzyme are 4000 bp and → When the DNA is digested with both BamH1 and HindIII enzymes, a total
Tube 1
Rube 2
Tube 3
DNA
BamHI
HindIII
BamHI
ladder
HindIII
compared to larger fragments.
determine the size of unknown DNA fragments.
resulting in the formation of two DNA fragments.
locations, producing three DNA fragments.
smallest DNA fragments compared to other restriction enzyme digestions.
5500 bp in length, while the fragments produced by HindIII are 8000 bp,
1000 bp, and 500 bp.
of four DNA fragments are produced, with sizes of 5500 bp, 2500 bp,
1000 bp, and 500 bp.
compared to larger fragments.
determine the size of unknown DNA fragments.
resulting in the formation of two DNA fragments.
locations, producing three DNA fragments.
smallest DNA fragments compared to other restriction enzyme digestions.
5500 bp in length, while the fragments produced by HindIII are 8000 bp,
1000 bp, and 500 bp.
of four DNA fragments are produced, with sizes of 5500 bp, 2500 bp,
1000 bp, and 500 bp.
COMMENT: 39% of responses received 0 or 1 mark
The codon table below can be used to determine amino acids coded for by a nucleotide sequence.
\( \textbf{lst position} \) \( \textbf{(5}^{′}\ \textbf{end)} \) \( \boldsymbol{\downarrow} \) |
\( \textbf{2nd position} \) |
\( \textbf{3rd position} \) \( \boldsymbol{\downarrow} \) |
|||
\( \textbf{U} \) | \( \textbf{C} \) | \( \textbf{A} \) | \( \textbf{G} \) | ||
\( \textbf{U} \) | \( \text{Phe}\) | \( \text{Ser}\) | \( \text{Tyr}\) | \( \text{Cys}\) | \( \textbf{U} \) |
\( \text{Phe}\) | \( \text{Ser}\) | \( \text{Tyr}\) | \( \text{Cys}\) | \( \textbf{C} \) | |
\( \text{Leu}\) | \( \text{Ser}\) | \( \text{STOP}\) | \( \text{STOP}\) | \( \textbf{A} \) | |
\( \text{Leu}\) | \( \text{Ser}\) | \( \text{STOP}\) | \( \text{Trp}\) | \( \textbf{G} \) | |
\( \textbf{C} \) | \( \text{Leu}\) | \( \text{Pro}\) | \( \text{His}\) | \( \text{Arg}\) | \( \textbf{U} \) |
\( \text{Leu}\) | \( \text{Pro}\) | \( \text{His}\) | \( \text{Arg}\) | \( \textbf{C} \) | |
\( \text{Leu}\) | \( \text{Pro}\) | \( \text{Gln}\) | \( \text{Arg}\) | \( \textbf{A} \) | |
\( \text{Leu}\) | \( \text{Pro}\) | \( \text{Gln}\) | \( \text{Arg}\) | \( \textbf{G} \) | |
\( \textbf{A} \) | \( \text{Ile}\) | \( \text{Thr}\) | \( \text{Asn}\) | \( \text{Ser}\) | \( \textbf{U} \) |
\( \text{Ile}\) | \( \text{Thr}\) | \( \text{Asn}\) | \( \text{Ser}\) | \( \textbf{C} \) | |
\( \text{Ile}\) | \( \text{Thr}\) | \( \text{Lys}\) | \( \text{Arg}\) | \( \textbf{A} \) | |
\( \text{Met}\) | \( \text{Thr}\) | \( \text{Lys}\) | \( \text{Arg}\) | \( \textbf{G} \) | |
\( \textbf{G} \) | \( \text{Val}\) | \( \text{Ala}\) | \( \text{Asp}\) | \( \text{Gly}\) | \( \textbf{U} \) |
\( \text{Val}\) | \( \text{Ala}\) | \( \text{Asp}\) | \( \text{Gly}\) | \( \textbf{C} \) | |
\( \text{Val}\) | \( \text{Ala}\) | \( \text{Glu}\) | \( \text{Gly}\) | \( \textbf{A} \) | |
\( \text{Val}\) | \( \text{Ala}\) | \( \text{Glu}\) | \( \text{Gly}\) | \( \textbf{G} \) |
It is correct to state
\(D\)
Consider each option:
Option A: The codon table shows that some codons code for different amino acids in
certain alternative translation systems → Incorrect
Option B: The genetic code is degenerate, meaning multiple codons can code for the
same amino acid, but this is not specific to Met → Incorrect
Option C: According to the codon table, the codon GGU codes for the amino acid
glycine (Gly), not tryptophan (Trp). The codon for Trp is UGG → Incorrect
Option D: Looking at the first position G, second position A, and third position A,
the codon GAA codes for the amino acid leucine (Leu) → Correct
\(\Rightarrow D\)
Damo hires paddle boats in summertime as part of his water sports business. To calculate the cost, \(C\), in dollars, of hiring \(x\) paddle boats, he uses the equation \(C=40+25x\).
He hires the paddle boats for $35 per hour and determines his income, \(I\), in dollars, using the equation \(I=35x\).
Use the graph to solve the two equations simultaneously for \(x\) and explain the significance of this solution for Damo's business. (2 marks)
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\(x=4\ \ \text{See worked solution}\)
\(\text{From the graph, intersection occurs at}\ x=4\)
\(\rightarrow\ \text{Break-even point occurs at}\ x=4\)
\(\text{i.e. when 4 hours of paddle board hire occurs}\)
\(\text{Income}\) | \(=35\times 4=$140\ \ \text{is equal to}\) |
\(\text{Costs}\) | \(=40+(25\times 4)=$140\) |
\(\text{If}\ <4\ \text{hours of board hire}\ \rightarrow\ \text{LOSS for business}\)
\(\text{If}\ >4\ \text{hours of board hire}\ \rightarrow\ \text{PROFIT}\)
The following table provides information on three commonly grown genetically modified (GM) crops in Australia.
\begin{array} {|l|l|l|}
\hline
\rule{0pt}{2.5ex} \quad \ \ \textbf{Crop} \rule[-1ex]{0pt}{0pt} & \quad \quad \textbf{Genetic modification} & \quad \ \textbf{Characteristic given by} \\
& & \quad \quad \quad \quad \textbf{modification} \rule[-1ex]{0pt}{0pt} \\
\hline
\rule{0pt}{2.5ex} \text{GM cotton} \rule[-1ex]{0pt}{0pt} & \text{several bacterial genes inserted} & \text{insect resistance and herbicide} \\
& & \text{tolerance} \rule[-1ex]{0pt}{0pt} \\
\hline
\rule{0pt}{2.5ex} \text{GM canola} \rule[-1ex]{0pt}{0pt} & \text{two genes from two different} & \text{tolerance to several herbicides} \\
& \text{bacterial species inserted} & \rule[-1ex]{0pt}{0pt}\\
\hline
\rule{0pt}{2.5ex} \text{GM safflower} \rule[-1ex]{0pt}{0pt} & \text{a selection of genes silenced within} & \text{elevated levels of oleic acid in its} \\
& \text{the safflower genome} & \text{seeds} \rule[-1ex]{0pt}{0pt} \\
\hline
\end{array}
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a. Answers should include one of the following:
→ GM cotton contains genes from other species or bacteria and is therefore transgenic.
→ GM canola contains genes from other species or bacteria and is therefore transgenic.
→ GM safflower does not contain genes from another species and is therefore not transgenic.
b. Possible answers include:
→ use alternative herbicides that the GM canola is not resistant to
→ digging out and removing roadside GM canola by hand
→ mowing the roadsides could help manage GM canola
→ burn the GM canola using controlled methods.
c. Social Implication – possible answers could include:
→ Depending on market demand non-GM canola farmers may see increased sales and improved quality of life, or decreased sales and lower quality of life.
→ GM canola farmers may benefit from higher yields and lower production costs may lead to increased profits and a better quality of life.
→ Consumers may benefit from improved nutrition that may lead to reduced strain on the healthcare system.
→ If GM canola becomes more affordable and accessible than alternative sources of nutrition, such as fish, a wider range of consumers will enjoy the health benefits.
→ Decreased consumption of fish due to the availability of cheaper, more accessible GM canola could lead to reduced sales and lower incomes for fish farmers, potentially decreasing their quality of life.
→ Some consumers may be hesitant to purchase or consume GM food products. This could lead to decreased demand for GM canola and lower incomes for farmers growing it.
Biological Implication – possible answers could include:
→ Crossbreeding between GM canola and non-GM canola crops could lead to changes in the genome of the crops which may reduce the genetic variation within the GM canola crop
→ Consumer safety concerns regarding consumption of GM products could negatively impact the demand for GM canola and other GM crops.
→ If GM canola leads to a reduction in fish consumption, it could have a positive impact on fish populations by reducing over-fishing. This could help to restore and maintain healthy fish populations in the long run.
→ Improved nutrition for consumers through the consumption of GM crops could lead to better health outcomes and improved well-being for the broader population.
a. Answers should include one of the following:
→ GM cotton contains genes from other species or bacteria and is therefore transgenic.
→ GM canola contains genes from other species or bacteria and is therefore transgenic.
→ GM safflower does not contain genes from another species and is therefore not transgenic.
b. Possible answers include:
→ use alternative herbicides that the GM canola is not resistant to
→ digging out and removing roadside GM canola by hand
→ mowing the roadsides could help manage GM canola
→ burn the GM canola using controlled methods.
c. Social Implication – possible answers could include:
→ Depending on market demand non-GM canola farmers may see increased sales and improved quality of life, or decreased sales and lower quality of life.
→ GM canola farmers may benefit from higher yields and lower production costs may lead to increased profits and a better quality of life.
→ Consumers may benefit from improved nutrition that may lead to reduced strain on the healthcare system.
→ If GM canola becomes more affordable and accessible than alternative sources of nutrition, such as fish, a wider range of consumers will enjoy the health benefits.
→ Decreased consumption of fish due to the availability of cheaper, more accessible GM canola could lead to reduced sales and lower incomes for fish farmers, potentially decreasing their quality of life.
→ Some consumers may be hesitant to purchase or consume GM food products. This could lead to decreased demand for GM canola and lower incomes for farmers growing it.
Biological Implication – possible answers could include:
→ Crossbreeding between GM canola and non-GM canola crops could lead to changes in the genome of the crops which may reduce the genetic variation within the GM canola crop
→ Consumer safety concerns regarding consumption of GM products could negatively impact the demand for GM canola and other GM crops.
→ If GM canola leads to a reduction in fish consumption, it could have a positive impact on fish populations by reducing over-fishing. This could help to restore and maintain healthy fish populations in the long run.
→ Improved nutrition for consumers through the consumption of GM crops could lead to better health outcomes and improved well-being for the broader population.
The short-beaked echidna can be found in Australia and New Guinea.
A university Biology student set out to compare DNA from four different short-beaked echidnas living in four different locations. The student aimed to determine the country of origin of each echidna. This was achieved using primers that amplified a 430 base pair (bp) sequence from the echidna's mitochondrial genome.
A flow chart of the steps taken by the student is shown below.
Which one of the following would be a requirement of either Step 1 or Step 2?
\(D\)
→ Polymerase chain reaction (PCR), step 2, needs two primers for the amplification of DNA.
→ Step 1 is the isolation of mtDNA, which is not present in the nucleus.
\(\Rightarrow D\)
The iron content in multivitamin tablets was determined using atomic absorption spectroscopy. The absorbances of four standards were measured. Three multivitamin tablets were selected. Each tablet was dissolved in 100.0 mL of water. The absorbance of each of the three solutions was then measured. The following absorbances were obtained. \begin{array}{|l|c|c|} --- 0 WORK AREA LINES (style=lined) --- --- 4 WORK AREA LINES (style=lined) --- Spectroscopic techniques work on the principle that, under certain conditions, atoms, molecules or ions will interact with electromagnetic radiation. The type of interaction depends on the wavelength of the electromagnetic radiation. --- 1 WORK AREA LINES (style=lined) --- --- 1 WORK AREA LINES (style=lined) --- --- 5 WORK AREA LINES (style=lined) --- a.i. a.ii. \(35.5\ \text{mg}\) b.i. Answers could include: → AAS (visible light) → UV-Vis (UV or visible light) → IR (Infrared radiation) → NMR (radio waves) b.ii. Spectroscopic technique: AAS (one of many possible – see b.i.) → During AAS energy of a certain frequency is transferred to electrons within atoms to move them into higher energy levels. → The absorption of the light indicates the concentration of the targeted element within the sample. a.i. a.ii. Average absorbance (tablets) \(=\dfrac{0.39+0.42+0.45}{3}=0.42\) Using the graph: absorbance value of \(0.42 → 355\ \text{mg L}^{-1}\) \(\ce{m(Fe) (100\ \text{ml}) = 355 \times 0.1 =35.5\ \text{mg}}\) b.i. Answers could include: → AAS (visible light) → UV-Vis (UV or visible light) → IR (Infrared radiation) → NMR (radiowaves) b.ii. Spectroscopic technique: AAS (one of many possible – see b.i.) → During AAS energy of a certain frequency is transferred to electrons within atoms to move them into higher energy levels. → The absorption of the light indicates the concentration of the targeted element within the sample.
\hline
\rule{0pt}{2.5ex}\quad \ \textbf{Solution} \rule[1ex]{0pt}{0pt} & \textbf{Concentration} & \textbf{Absorbance} \\
& \textbf{mg/L} & \\
\hline
\rule{0pt}{2.5ex} \text{Standard 1} \quad \quad & 0.00 & 0.06 \\
\hline
\rule{0pt}{2.5ex} \text{Standard 2} & 100.0 & 0.16 \\
\hline
\rule{0pt}{2.5ex} \text{Standard 3} & 200.0 & 0.25 \\
\hline
\rule{0pt}{2.5ex} \text{Standard 4} & 300.0 & 0.36 \\
\hline
\rule{0pt}{2.5ex} \text{Standard 5} & 400.0 & 0.46 \\
\hline
\rule{0pt}{2.5ex} \text{Tablet 1} & - & 0.39 \\
\hline
\rule{0pt}{2.5ex} \text{Tablet 2} & - & 0.42 \\
\hline
\rule{0pt}{2.5ex} \text{Tablet 3} & - & 0.45 \\
\hline
\end{array}
Bec is a baker and makes cookies to sell every week.
The cost of making \(n\) cookies, $\(C\), can be calculated using the equation
\(C=400+2.5n\)
Bec sells the cookies for $4.50 each, and her income is calculated using the equation
\(I=450n\)
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Jake and Preston are planning a fund-raising event at the local swim centre. They can have access to the giant pool float for $550 and the party room hire for $250. A sausage sizzle and drinks will cost them $9 per person.
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The graph shows planned income and costs when the ticket price is $15.
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Jake and Preston have 300 tickets to sell. They want to make a profit of $1510.
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i. | \($C\) | \(=550+250+(9\times x)\) |
\(=800+9x\) |
ii. \(\text{Using the graph intersection}\)
\(\text{Approximately 135 people are needed}\)
\(\text{to cover the costs.}\)
iii. \(\text{If 200 people attend}\)
\(\text{Income}\) | \(=200\times $15\) |
\(=$3000\) |
\(\text{Costs}\) | \(=800+(9\times 200)\) |
\(=$2600\) |
\(\therefore\ \text{Profit}\) | \(=3000-2600\) |
\(=$400\) |
iv. \(\text{Costs when}\ x=300:\)
\(C\) | \(=800+(9\times 300)\) |
\(=$3500\) |
\(\text{Income required to make }$1510\ \text{profit}\)
\(=3500+1510\)
\(=$5010\)
\(\therefore\ \text{Price per ticket}\) | \(=\dfrac{5010}{300}\) |
\(=$16.70\) |
There are two tanks at an industrial plant, Tank A and Tank B. Initially, Tank A holds 2520 litres of liquid fertiliser and Tank B is empty.
The volume of liquid fertiliser in Tank A is modelled by \(V=1400-40t\) where \(V\) is the volume in litres and \(t\) is the time in minutes from when the tank begins to drain the fertiliser.
On the grid below, draw the graph of this model and label it as Tank A. (1 mark)
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a. \(\text{Tank} \ A \ \text{will pass through (0, 1400) and (35, 0)}\)
b. \(\text{Tank} \ B \ \text{will pass through (10, 0) and (30, 1200)}\)
\(\text{By inspection, the two graphs intersect at} \ \ t = 20 \ \text{minutes}\)
c. \(\text{Strategy 1}\)
\(\text{By inspection of the graph, consider} \ \ t = 30\)
\(\text{Tank A} = 200 \ \text{L} , \ \text{Tank B} =1200 \ \text{L}\)
\(\therefore\ \text{Total volume = 1400 L when t = 30}\)
\(\text{Strategy 2}\)
\(\text{Total Volume}\) | \(=\text{Tank A} + \text{Tank B}\) |
\(1400\) | \(=1400-40t+(t-10)\times 60\) |
\(1400\) | \(=1400-40t+60t-600\) |
\(20t\) | \(= 600\) |
\(t\) | \(= 30 \ \text{minutes}\) |
A small business makes and dog kennels.
Technology was used to draw straight-line graphs to represent the cost of making the dog kennels \((C)\) and the revenue from selling dog kennels \((R)\). The \(x\)-axis displays the number of dog kennels and the \(y\)-axis displays the cost/revenue in dollars.
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a. \(20\ \ (x\text{-value at intersection})\)
b. \(\text{Find equations of both lines}:\)
\((0, 400)\ \text{and}\ (20, 600)\ \text{lie on}\ \ C\)
\(\text{gradient}_C = \dfrac{600-400}{20-0}=10\)
\(\rightarrow\ C=400+10x\)
\((0,0)\ \text{and}\ (20, 600)\ \text{lie on}\ \ R\)
\(\text{gradient}_R =\dfrac{600-0}{20-0}=30\)
\(\rightarrow\ R=30x\)
\(\text{Profit} = R-C\)
\(\text{Find}\ \ x\ \text{when Profit }= $2500:\)
\(2500\) | \(=30x-(400+10x)\) |
\(20x\) | \(=2900\) |
\(x\) | \(=145\) |
\(\therefore\ 145\ \text{dog kennels need to be sold to earn }$2500\ \text{profit}\)
Uri drew a correct diagram that gave the solution to the simultaneous equations
\(y=2x+3\) and \(y=x+4\).
Which diagram did he draw?
\(D\)
\(\text{By elimination:}\)
\(y=2x+3\ \text{cuts the }y \text{-axis at}\ 3\)
\(\rightarrow\ \text{Eliminate be A and B}\)
\(y=x+4\ \text{cuts the }y\text{-axis at}\ 4\)
\(\text{AND has a positive gradient}\)
\(\rightarrow\ \text{Eliminate C}\)
\(\Rightarrow D\)
A function centre hosts events for up to 500 people. The cost \(C\), in dollars, for the centre
to host an event, where \(x\) people attend, is given by:
\(C=20\ 000+40x\)
The centre charges $120 per person. Its income \(I\), in dollars, is given by:
\(I=120x\)
How much greater is the income of the function centre when 500 people attend an event, than its income at the breakeven point?
\(C\)
\(\text{When}\ x=500,\ I=120\times 500=$60\ 000\)
\(\text{Breakeven when}\ \ x=250\ \ \text{(from graph)}\)
\(\text{When}\ \ x=250,\ I=120\times 250=$30\ 000\)
\(\text{Difference}\) | \(=60\ 000-30\ 000\) |
\(=$30\ 000\) |
\(\Rightarrow C\)
The volume of water in a tank changes over six months, as shown in the graph.
Consider the overall decrease in the volume of water.
What is the average percentage decrease in the volume of water per month over this time, to the nearest percent?
\(B\)
\(\text{Initial Volume}\) | \(=50\ 000\ \text{L}\) |
\(\text{Final volume}\) | \(=15\ 000\ \text{L}\) |
\(\text{Decrease}\) | \(=50\ 000-15\ 000\) |
\(=35\ 000\ \text{L (over 6 months)}\) |
\(\text{Loss per month}\) | \(=\dfrac{35\ 000}{6}\) |
\(=5833.33\dots\ \text{L per month}\) | |
\(\text{% loss per month}\) | \(=\dfrac{5833.33\dots}{50\ 000}\times 100\%\) |
\(=11.666\dots \%\) |
\(\Rightarrow B\)
A factory makes both cloth and leather lounges. In any week
• the total number of cloth lounges and leather lounges that are made is 400
• the maximum number of leather lounges made is 270
• the maximum number of cloth lounges made is 325.
The factory manager has drawn a graph to show the numbers of leather lounges (\(x\)) and cloth lounges (\(y\)) that can be made.
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Compare the profits at \(B\) and \(C\). (2 marks)
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\(\rightarrow\ x\ \text{cannot be}\ >270\)
\(\text{Since the max amount of cloth lounges}=325\)
\(\rightarrow\ y\ \text{cannot be}\ >325\)
\(\therefore\ \text{The line}\ AD\ \text{is only possible between}\ B\ \text{and}\ C.\)
i. \(\text{We are told the number of leather lounges}\ (x),\)
\(\text{and cloth lounges}\ (y),\ \text{made in any week} = 400\)
\(\rightarrow\ \text{Equation of}\ AD\ \text{is}\ x+y=400\)
ii. \(\text{Since the max amount of leather lounges}=270\)
\(\rightarrow\ x\ \text{cannot}\ >270\)
\(\text{Since the max amount of cloth lounges}=325\)
\(\rightarrow\ y\ \text{cannot}\ >325\)
\(\therefore\ \text{The line}\ AD\ \text{is only possible between}\ B\ \text{and}\ C.\)
iii. \(\text{At}\ B,\ x=75,\ y=325\)
\(\rightarrow\ $P (\text{at}\ B)\) | \(=2520\times 75+1570\times 325\) |
\(=189\ 000+510\ 250\) | |
\(=$699\ 250\) |
\(\text{At}\ C,\ x=270,\ y=130\)
\(\rightarrow\ $P (\text{at}\ C)\) | \(=2520\times 270+1570\times 130\) |
\(=680\ 400+204\ 100\) | |
\(=$884\ 500\) |
\(\text{Difference in profits}=$884\ 500-$699\ 250=$185\ 250\)
\(\text{The profits at}\ C\ \text{are } $185\ 250\ \text{more than at}\ B.\)
The graph shows tax payable against taxable income, in thousands of dollars.
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i. |
\(\text{Income on}\ $18\ 000=$3000\ \ \text{(from graph)}\)
ii. \(\text{Using the points}\ (18, 3)\ \text{and}\ (33, 10)\)
\(\text{Gradient at}\ A\) | \(=\dfrac{y_2-y_1}{x_2-x_1}\) |
\(=\dfrac{10\ 000-3000}{33\ 000-18\ 000}\) | |
\(=\dfrac{7000}{15\ 000}\) | |
\(=\dfrac{7}{15}\ \ \ \ \text{… as required}\) |
iii. \(\text{The gradient represents the tax applicable on each dollar}\)
\(\text{Tax}\) | \(=\dfrac{7}{15}\ \text{of each dollar earned}\) |
\(=46\frac{2}{3}\approx 47\ \text{cents per dollar earned (nearest whole number)}\) |
iv. \(\text{Tax payable up to }$18\ 000 = $3000\)
\(\text{Tax payable on income between }$18\ 000\ \text{and }$33\ 000\)
\(=\dfrac{7}{15}(I-18\ 000)\)
\(\therefore\ \text{Tax payable →}\ \ T\) | \(=3000+\dfrac{7}{15}(I-18\ 000)\) |
\(=3000+\dfrac{7}{15} I-8400\) | |
\(=\dfrac{7}{15}I-5400\) |
A cafe uses eight long-life light globes for 7 hours every day of the year. The purchase price of each light globe is $11.00 and they each cost \($f\) per hour to run.
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i. \(\text{Purchase price}=8\times 11=$88\)
\(\text{Running cost}\) | \(=\text{No. of hours}\times \text{Cost per hour}\) |
\(=8\times 7\times 365\times f\) | |
\(=20\ 440f\) |
\(\therefore\ $c=88+20\ 440f\)
ii. \(\text{Given}\ \ $c=$850\)
\(850\) | \(=88+20\ 440f\) |
\(20\ 440f\) | \(=850-88\) |
\(f\) | \(=\dfrac{762}{20440}\) |
\(= 0.03727\dots\) | |
\(=0.037\ $/\text{hr}\ \text{(3 d.p.)}\) |
iii. \(\text{If}\ f\ \text{is multiplied by }1.5 =\dfrac{10.5}{7}\)
\(f=1.5\times0.037=0.0555\ \ $/\text{hr}\)
\(\therefore\ $c\) | \(=88+20\ 440\times 0.0555\) |
\(=$1222.42\) |
\(\text{Since }$1222.42\ \text{is less than}\ 1.5\times $850 = $1275,\)
\(\text{the total cost increases to less than 1.5 times the}\)
\(\text{the original cost.}\)
Mary-Anne knows that
• one Australian dollar (AUD) is worth 0.64 euros, and
• one Canadian dollar (CAD) is worth 0.97 euros.
Mary-Anne changes 75 AUD to Canadian dollars.
How many Canadian dollars will she get?
\(B\)
\(\text{Mary-Anne has 75 AUD.}\)
\(\text{Converting to Euros}\)
\(25\ \text{AUD}\) | \(=75\times 0.64\) |
\(=48\ \text{Euros}\) |
\(\text{Converting to CAD}\)
\(48\ \text{euros}\) | \(=\dfrac{48}{0.97}\) |
\(=49.484\dots\) | |
\(=49.48\ \text{CAD}\) |
\(\Rightarrow B\)
The graph shows the life expectancy of people born between 1900 and 2010.
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i. \(\text{76 years}\)
ii. \(\text{Using (2000, 88) and (1900, 50):}\)
\(\text{Gradient}\) | \(= \dfrac{y_2-y_1}{x_2-x_1}\) |
\(= \dfrac{88-50}{2000-1900}\) | |
\(= 0.38\) |
\(\text{After 1900, life expectancy increases by 0.38 years for}\)
\(\text{each year later that someone is born.}\)
The cost of apples per kilogram, \(C\), varies directly with the weight of apples purchased, \(w\).
If 12 kilograms costs $56.64, calculate the cost of 4.5 kilograms of apples. (2 marks)
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\($21.24\)
\(C\ \propto \ w\)
\(C=kw\)
\(\text{When}\ C=$56.64\ \text{kg},\ w=12\ \text{kg}\)
\(56.64\) | \(=k\times 12\) |
\(k\) | \(=\dfrac{56.64}{12}\) |
\(=$4.72\) |
\(\text{When}\ \ w=4.5\ \text{kg,}\)
\(C\) | \(=4.72\times 4.5\) |
\(=$21.24\) |
The average height, \(L\), in centimetres, of a boy between the ages of 7 years and 10 years can be represented by a line with equation
\(L=7A+85\)
where \(A\) is the age in years. For this line, the gradient is 7.
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i. \(\text{It indicates that 7-10 year old boys, on average, grow}\)
\(\text{7 cm per year.}\)
ii. \(\text{Boys eventually stop growing, and the equation doesn’t}\)
\(\text{factor this in.}\)
The relationship between British pounds \((p)\) and Australian dollars \((d)\) on a particular day is shown in the graph.
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Convert \(107\ 520\) Japanese yen to British pounds. (2 marks)
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a. \(m=\dfrac{\text{rise}}{\text{run}}=\dfrac{5}{8}\)
\(p=\dfrac{5}{8}d\)
b. \(\text{Yen to Australian dollars:}\)
\(y\) | \(=84d\) |
\(107\ 520\) | \(=84d\) |
\(d\) | \(=\dfrac{107\ 520}{84}\) |
\(= 1280\ $\text{A}\) |
\(\text{Australian dollars to pounds:}\)
\(p\) | \(=\dfrac{5}{8}\times 1280\) |
\(=800\ \text{pounds}\) |
\(\therefore\ 107\ 520\ \text{yen = 800 pounds}\)
The diagram shows a container which consists of a large hexagonal prism on top of a smaller hexagonal prism.
The container is filled with water at a constant rate into the top of the larger hexagonal prism.
The smaller prism is totally filled before the larger prism begins to fill.
It takes 5 minutes to fill the smaller cylinder.
Draw a possible graph of the water level in the container against time. (2 marks)
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An electrician charges a call-out fee of $75 as well as $1.50 per minute while working.
Suppose the electrician works for \(t\) hours.
Which equation expresses the amount the plumber charges ($\(C\)) as a function of time (\(t\) hours)?
\(C\)
\(\text{Hourly rate}=60\times 1.50=$90\)
\(\therefore\ C=75+90t\)
\(\Rightarrow C\)
The height of a bundle of photographic paper (\(H\) mm) varies directly with the number of sheets (\(N\)) of photographic paper that the bundle contains.
This relationship is modelled by the formula \(H=kN\), where \(k\) is a constant.
The height of a bundle containing 150 sheets of photographic paper is 2.7 centimetres.
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a. \(H=2.7\ \text{cm }=27\ \text{mm, when}\ N=150:\)
\(H\) | \(=kN\) |
\(2.7\) | \(=k\times 150\) |
\(\therefore\ k\) | \(=\dfrac{2.7}{150}\) |
\(=0.18\) |
b. \(\text{Find}\ \ N \ \text{when} \ \ H=36\ \text{cm}=360\ \text{mm:}\)
\(360\) | \(=0.18\times N\) |
\(\therefore\ N\) | \(=\dfrac{360}{0.18}\) |
\(=2000\ \text{sheets}\) |
The line below has intercepts \(m\) and \(n\), where \(m\) and \(n\) are positive integers.
What is the gradient of the line?
\(C\)
\(\text{Gradient}\) | \(=\dfrac{\text{rise}}{\text{run}}\) |
\(=-\dfrac{m}{n}\) |
\(\Rightarrow C\)
If \(C=5x+4\), and \(x\) is increased by 3, what will be the corresponding increase in \(C\) ?
\(B\)
\(C=5x+4\)
\(\text{If}\ x\ \text{increases by 3}\)
\(C\ \text{increases by}\ 5\times 3=15\)
\(\Rightarrow B\)
Which of the following is the graph of \(y=-3x-3\)?
A. | B. | ||
C. | D. |
\(A\)
\(y=-3x-3\)
\(\text{By elimination:}\)
\(\ y\text{-intercept}=-3\)
\(\rightarrow\ \text{Cannot be}\ B\ \text{or}\ D\)
\(\text{Gradient}=-3\)
\(\rightarrow\ \text{Cannot be}\ C\)
\(\Rightarrow A\)
The time for a car to travel a certain distance varies inversely with its speed.
Which of the following graphs shows this relationship?
`A`
`T` | `prop 1/S` |
`T` | `= k/S` |
`text{By elimination:}`
`text(As S) uarr text(, T) darr => text(cannot be B or D)`
`text(C is incorrect because it graphs a linear relationship)`
`=> A`
Sticks were used to create the following pattern.
The number of sticks used is recorded in the table.
\begin{array} {|l|c|}
\hline
\rule{0pt}{2.5ex} \text{Shape $(S)$} \rule[-1ex]{0pt}{0pt} & \;\;\; 1 \;\;\; & \;\;\; 2 \;\;\; & \;\;\; 3 \;\;\; \\
\hline
\rule{0pt}{2.5ex} \text{Number of sticks $(N)$}\; \rule[-1ex]{0pt}{0pt} & \;\;\; 6 \;\;\; & \;\;\; 10 \;\;\; & \;\;\; 14 \;\;\; \\
\hline
\end{array}
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Show suitable calculations to support your answer. (2 marks)
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i. \(\text{Shape 4 is shown below:}\)
ii. \(\text{Since}\ \ N=2+4S\)
\(\text{If }S\) | \(=128\) |
\(N\) | \(=2+(4\times 128)\) |
\(=514\) |
iii. | \(609\) | \(=2+4S\) |
\(4S\) | \(=607\) | |
\(S\) | \(=151.75\) |
\(\text{Since}\ S\ \text{is not a whole number, 609 sticks}\)
\(\text{will not create a shape in this pattern.}\)
The total cost, \($C\), of a school excursion is given by \(C=4n+9\), where \(n\) is the number of students.
If five extra students go on the excursion, by how much does the total cost increase?
\(B\)
\(C=4n+9\)
\(\text{If}\ n\ \text{increases to}\ n+5\)
\(C\) | \(=4(n+5)+9\) |
\(=4n+20+9\) | |
\(=4n+29\) |
\(\therefore \text{Total cost increases by }$20\)
\(\Rightarrow B\)
What is the equation of the line \(l\)?
\(C\)
\(l\ \ \text{passes through (0, 5) and (1, 0)}\)
\(\text{Gradient}\) | \(=\dfrac{y_2-y_1}{x_2-x_1}\) |
\(=\dfrac{5-0}{0-1}\) | |
\(=-5\) |
\(y\ \text{-intercept}= 5\)
\(\therefore\ y=-5x+5\)
\(\Rightarrow C\)
A pentagon is created using matches.
By adding more matches, a row of two pentagons is formed.
Continuing to add matches, a row of three pentagons can be formed.
Continuing this pattern, what is the maximum number of complete pentagons that can be formed if 230 matches in total are available?
\(C\)
\(\text{1 pentagon:}\ 5+4\times 0=5\)
\(\text{2 pentagons:}\ 5+4\times 1=9\)
\(\text{3 pentagons:}\ 5+4\times 2 = 13\)
\(\vdots\)
\(n\ \text{pentagons:}\ 5 + 4(n – 1)\)
\(5+4(n – 1)\) | \(=230\) |
\(4n-4\) | \(=225\) |
\(4n\) | \(=229\) |
\(n\) | \(=57.25\) |
\(\text{Complete pentagons possible}\ =57\)
\(\Rightarrow C\)
Which of the following could be the graph of \(y=-2-2x\)?
\(B\)
\(\text{By elimination:}\)
\(y\text{-intercept} =-2\ \rightarrow\ \text{Eliminate}\ A \text{ and}\ D\)
\(\text{Gradient is negative}\ \rightarrow\ \text{Eliminate}\ C\)
\(\Rightarrow B\)
A train departs from Town A at 4.00 pm to travel to Town B. Its average speed for the journey is 80 km/h, and it arrives at 6.00 pm. A second train departs from Town A at 4.30 pm and arrives at Town B at 6.10 pm.
What is the average speed of the second train?
\(A\)
\(\text{1st train:}\)
\(\text{Travels 2hrs at 80km/h}\)
\(\text{Distance}\) | \(=\text{Speed}\times\text{Time}\) |
\(=80\times 2\) | |
\(=160\ \text{km}\) |
\(\text{2nd train:}\)
\(\text{Travels 160 km in 1 hr 40 min}\ \rightarrow\ \dfrac{5}{3}\ \text{hrs}\)
\(\text{Speed}\) | \(=\dfrac{\text{Distance}}{\text{Time}}\) |
\(=160\ ÷\ \dfrac{5}{3}\) | |
\(=160\times \dfrac{3}{5}\) | |
\(=96\ \text{km/h}\) |
\(\Rightarrow A\)
The time for a train to travel a certain distance varies inversely with its speed.
Which of the following graphs shows this relationship?
\(C\)
\(T\) | \(\propto \dfrac{1}{S}\) |
\(T\) | \(=\dfrac{k}{S}\) |
\(\text{By elimination:}\)
\(\text{As Speed} \uparrow \ \text{, Time}\downarrow\ \Rightarrow\ \text{cannot be A or B}\)
\(\text{D is incorrect because it graphs a linear relationship}\)
\(\Rightarrow C\)
Young’s formula below is used to calculate the required dosages of medicine for children aged 1–12 years.
\(\text{Dosage}=\dfrac{\text{age of child (in years)}\ \times\ \text{adult dosage}}{\text{age of child (in years)}\ +\ 12}\)
How much of the medicine should be given to an 18-month-old child in a 24-hour period if each adult dosage is 27 mL? The medicine is to be taken every 8 hours by both adults and children.
\(C\)
\(\text{Age of child} = 18\ \text{months}=1.5\ \text{years}\)
\(\text{Dosage}\) | \(=\dfrac{1.5\times 27}{1.5+12}\) |
\(=3\ \text{mL}\) |
\(\text{Dosage every 8 hrs}\)
\(\therefore\ \text{In 24 hours, medicine given} = 3\times 3=9\ \text{mL}\)
\(\Rightarrow C\)
Monica is driving on a motorway at a speed of 105 kilometres per hour and has to brake suddenly. She has a reaction time of 1.3 seconds and a braking distance of 54.3 metres.
Stopping distance can be calculated using the following formula
\(\text{stopping distance = {reaction time distance} + {braking distance}}\)
What is Monica's stopping distance? Give your answer to 1 decimal place. (2 marks)
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\(92.2\ \text{metres (to 1 d.p.)}\)
\(105\ \text{km/hr}\) | \(=105\ 000\ \text{m/hr}\) |
\(=\dfrac{105\ 000}{60\times 60}\ \text{m/sec}\) | |
\(=29.166\dots\ \text{m/sec}\) |
\(\text{Reaction time distance}\) | \(=1.3\times 29.166\dots\) |
\(=37.916\dots\ \text{metres}\) |
\(\text{Stopping distance}\)
\(\text{ = {Reaction time distance} + {braking distance}}\)
\(=37.916…+54.3\)
\(=92.216\dots\)
\(=92.2\ \text{metres (to 1 d.p.)}\)
Yuan is driving in a school zone at a speed of 30 kilometres per hour and needs to stop immediately to avoid an accident.
It takes him 1.4 seconds to react and his breaking distance is 6.2 metres.
Stopping distance can be calculated using the following formula
\(\text{stopping distance = {reaction time distance} + {braking distance}}\)
What is Yuan's total stopping distance? Give your answer to 1 decimal place. (2 marks)
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\(17.9\ \text{metres (to 1 d.p.)}\)
\(30\ \text{km/hr}\) | \(=30\ 000\ \text{m/hr}\) |
\(=\dfrac{30\ 000}{60\times 60}\ \text{m/sec}\) | |
\(=8.33\dots\ \text{m/sec}\) |
\(\therefore\ \text{Total stopping distance}\)
\(\text{ = {Reaction time distance} + {braking distance}}\)
\(=1.4\times 8.33…+6.2\)
\(=17.866\dots\)
\(=17.9\ \text{metres (to 1 d.p.)}\)
Drake is driving at 80 km/h. He notices a branch on the road ahead and decides to apply the brakes. His reaction time is 1.2 seconds. His braking distance (\(D\) metres) is given by \(D=0.01v^2\), where \(v\) is speed in km/h.
Stopping distance can be calculated using the following formula
\(\text{stopping distance = {reaction time distance} + {braking distance}}\)
What is Drake’s stopping distance, to the nearest metre? (3 marks)
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\(91\ \text{m (nearest m)}\)
\(\text{80 km/hr}\) | \(=80\ 000\ \text{m/hr}\) |
\(=\dfrac{80\ 000}{60\times 60}\ \text{m/sec}\) | |
\(=22.22\dots\ \text{m/sec}\) |
\(\text{Total stopping distance}\)
\(\text{ = {reaction time distance} + {braking distance}}\)
\(=1.2\times 22.22\dots + 0.01\times 80^2\)
\(=90.66\dots\)
\(=91\ \text{m (nearest m)}\)
Jeremy tried to solve this equation and made a mistake in Line 2.
\(\dfrac{M+3}{2}-\dfrac{2M-1}{5}\) | \(=1\) | \(\text{... Line 1}\) |
\(5M+15-4M-2\) | \(=10\) | \(\text{... Line 2}\) |
\(M+13\) | \(=10\) | \(\text{... Line 3}\) |
\(M\) | \(=-3\) | \(\text{... Line 4}\) |
Copy the equation in Line 1 and continue your solution to solve this equation for \(M\).
Show all lines of working. (2 marks)
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\(\dfrac{M+3}{2}-\dfrac{2M-1}{5}\) | \(=1\) | `text(… Line 1)` |
\(5M+15-4M+2\) | \(=10\) | `text(… Line 2)` |
\(M+17\) | \(=10\) | `text(… Line 3)` |
\(M\) | \(=-7\) | `text(… Line 4)` |
\(\dfrac{M+3}{2}-\dfrac{2M-1}{5}\) | \(=1\) | `text(… Line 1)` |
\(5M+15-4M+2\) | \(=10\) | `text(… Line 2)` |
\(M+17\) | \(=10\) | `text(… Line 3)` |
\(M\) | \(=-7\) | `text(… Line 4)` |
If \(M=-8\), what is the value of \(\dfrac{4M^2+3M}{8}\)
\(C\)
\(\dfrac{4M^2+3M}{8}\) | \(=\dfrac{4\times (-8)^2+3\times (-8)}{8}\) |
\(=\dfrac{4\times 64-24}{8}\) | |
\(=\dfrac{232}{8}\) | |
\(=29\) |
\(\Rightarrow C\)
Solve the equation \(\dfrac{3x}{4}+1=\dfrac{5x+1}{3}\), leaving your answer as a fraction. (3 marks)
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\(\dfrac{8}{11}\)
\(\underbrace{\dfrac{3x}{4} + 1}_\text{multiply x 12}\) | \(=\underbrace{\dfrac{5x+1}{3}}_\text{multiply x 12}\) |
\(9x+12\) | \(=20x+4\) |
\(11x\) | \(=8\) |
\(x\) | \(=\dfrac{8}{11}\) |
Solve \(x+\dfrac{x-3}{4}=5\), leaving your answer as a fraction. (2 marks)
\(\dfrac{23}{5}\)
\(x+\dfrac{x-3}{4}\) | \(=5\) |
\(4x+x-3\) | \(=20\) |
\(5x\) | \(=23\) |
\(x\) | \(=\dfrac{23}{5}\) |
Which equation correctly shows \(n\) as the subject of \(V=600(1-n)\)?
\(B\)
\(V\) | \(=600(1-n)\) |
\(1-n\) | \(=\dfrac{V}{600}\) |
\(n\) | \(=1-\dfrac{V}{600}\) |
\(=\dfrac{600-V}{600}\) |
\(\Rightarrow B\)
Which of the following correctly expresses \(b\) as the subject of \(y= ax+\dfrac{1}{4}bx^2\)?
\(B\)
\(y\) | \(= ax+\dfrac{1}{4}bx^2\) |
\(\dfrac{1}{4}bx^2\) | \(=y-ax\) |
\(bx^2\) | \(=4(y-ax)\) |
\(b\) | \(=\dfrac{4(y-ax)}{x^2}\) |
\(\Rightarrow B\)
What is the formula for \(g\) as the subject of \(7d=8e+5g^2\)?
\(B\)
\(7d\) | \(=8e+5g^2\) |
\(5g^2\) | \(=7d-8e\) |
\(g^2\) | \(=\dfrac{7d-8e}{5}\) |
\(g\) | \(=\pm\sqrt{\dfrac{7d-8e}{5}}\) |
\(\Rightarrow B\)
Which of the following correctly expresses \(X\) as the subject of \(Y=4\pi\Bigg(\dfrac{X}{4}+L\Bigg)\)?
\(B\)
\(Y\) | \(=4\pi\Bigg(\dfrac{X}{4}+L\Bigg)\) |
\(\dfrac{Y}{4\pi}\) | \(=\dfrac{X}{4}+L\) |
\(\dfrac{X}{4}\) | \(=\dfrac{Y}{4\pi}-L\) |
\(X\) | \(=4\Bigg(\dfrac{Y}{4\pi}-L\Bigg)\) |
\(X\) | \(=\dfrac{Y}{\pi}-4L\) |
\(\Rightarrow B\)
Make \(r\) the subject of the equation \(V=4\pi r^2\). (2 marks)
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\(r=\pm\sqrt{\dfrac{V}{4\pi}}\)
\(V\) | \(=4\pi r^2\) |
\(r^2\) | \(=\dfrac{V}{4\pi}\) |
\(\therefore\ r\) | \(=\pm\sqrt{\dfrac{V}{4\pi}}\) |
Make \(b\) the subject of the equation \(a=\sqrt{bc-4}\). (2 marks)
\(b=\dfrac{a^2+4}{c}\)
\(a\) | \(=\sqrt{bc-4}\) |
\(a^2\) | \(=bc-4\) |
\(bc\) | \(=a^2+4\) |
\(\therefore\ b\) | \(=\dfrac{a^2+4}{c}\) |
Which of the following correctly expresses \(y\) as the subject of the formula \(5x-2y-9=0\)?
\(D\)
\(5x-2y-9\) | \(=0\) |
\(2y\) | \(=5x-9\) |
\(\therefore\ y\) | \(=\dfrac{5x-9}{2}\) |
\(\Rightarrow D\)
A chemist uses spectroscopy to identify an unknown organic molecule, Molecule \(\text{J}\), that contains chlorine. The \({}^{13}\text{C NMR}\) spectrum of Molecule \(\text{J}\) is shown below. The infra-red (IR) spectrum of Molecule \(\text{J}\) is shown below. --- 2 WORK AREA LINES (style=lined) --- The mass spectrum of Molecule \(\text{J}\) is shown below --- 2 WORK AREA LINES (style=lined) --- The \({ }^1 \text{H NMR}\) spectrum of Molecule \(\text{J}\) is shown below. --- 3 WORK AREA LINES (style=lined) --- --- 5 WORK AREA LINES (style=blank) --- a. → Absence of a very broad \(\ce{OH}\) acid peak between 2500–3000. → Molecule \(\text{J}\) must be an ester. b. The peak at 110 m/z: → due to the Chlorine-37 isotope which is slightly heavier than the more abundant Chlorine-35. c. The two singlet peaks indicate: → two different hydrogen environments within the molecule. → there are no adjacent hydrogen environments. → The relative heights of the peaks show the ratios of the hydrogens in the environments are 2 : 3. d. Either of the two molecules show below are correct: a. → Absence of a very broad \(\ce{OH}\) acid peak between 2500–3000. → Molecule \(\text{J}\) must be an ester. b. The peak at 110 m/z: → due to the Chlorine-37 isotope which is slightly heavier than the more abundant Chlorine-35. c. The two singlet peaks indicate: → two different hydrogen environments within the molecule. → there are no adjacent hydrogen environments. → The relative heights of the peaks show the ratios of the hydrogens in the environments are 2 : 3. d. Either of the two molecules show below are correct:
COMMENT: Know the masses of common isotopes.
Two students are given a homework assignment that involves analysing a set of spectra and identifying an unknown compound. The unknown compound is one of the molecules shown below. The \(^{13}\text{C NMR}\) spectrum of the unknown compound is shown below. --- 1 WORK AREA LINES (style=lined) --- --- 6 WORK AREA LINES (style=lined) --- --- 1 WORK AREA LINES (style=lined) --- --- 4 WORK AREA LINES (style=lined) ---
a. → The \(^{13}\text{C NMR}\) shows 4 different carbon environments. → Compound \(T\) has 5 unique carbon environments and can be eliminated. b. → Compounds \(\text{P, Q}\) and \(\text{S}\) can be eliminated. → Compounds \(\text{S}\) and \(\text{P}\) both don’t have an \(\ce{OH}\) alcohol group, however the IR spectrum clearly shows an \(\ce{OH}\) alcohol group with an absorbance at 3500 cm\(^{-1}\). → Compound \(\text{Q}\) contains an \(\ce{OH}\) acid group whereas the IR spectrum shows an \(\ce{OH}\) alcohol group at 3500 cm\(^{-1}\). There is no evidence of a broad \(\ce{OH}\) acid group between 2500–3000 cm\(^{-1}\). c.i. → The unknown compound is compound \(\text{R}\). → The chemical species are fragments of the original compound with a positive charge. → The chemical formulas could include \(\ce{[CH3CO]^+}\) or \(\ce{[C2H3O]^+}\) ii. → Ions of that molecule must be formed to produce peaks on the mass spectrum. → Organic compounds can be split up into numerous different ions when producing fragment patterns leading to multiple different peaks on the mass spectrum.
a. → The \(^{13}\text{C NMR}\) shows 4 different carbon environments. → Compound \(T\) has 5 unique carbon environments and can be eliminated. b. → Compounds \(\text{P, Q}\) and \(\text{S}\) can be eliminated. → Compounds \(\text{S}\) and \(\text{P}\) both don’t have an \(\ce{OH}\) alcohol group, however the IR spectrum clearly shows an \(\ce{OH}\) alcohol group with an absorbance at 3500 cm\(^{-1}\). → Compound \(\text{Q}\) contains an \(\ce{OH}\) acid group whereas the IR spectrum shows an \(\ce{OH}\) alcohol group at 3500 cm\(^{-1}\). There is no evidence of a broad \(\ce{OH}\) acid group between 2500–3000 cm\(^{-1}\). c.i. → The unknown compound is compound \(\text{R}\). → The chemical species are fragments of the original compound with a positive charge. → The chemical formulas could include \(\ce{[CH3CO]^+}\) or \(\ce{[C2H3O]^+}\) ii. → Ions of that molecule must be formed to produce peaks on the mass spectrum. → Organic compounds can be split up into numerous different ions when producing fragment patterns leading to multiple different peaks on the mass spectrum.
COMMENT: Recognise the difference between OH alcohols and OH acid groups.
COMMENT: Ions require a positive charge.
Molecule \(\text{V}\) contains only carbon atoms, hydrogen atoms and one oxygen atom. The mass spectrum of molecule \(\text{V}\) is shown below.
--- 4 WORK AREA LINES (style=lined) --- --- 1 WORK AREA LINES (style=lined) --- The \({ }^1 \text{H NMR}\) spectrum of molecule \(\text{V}\) is shown below.
--- 2 WORK AREA LINES (style=lined) --- The \({ }^{13} \text{C NMR}\) spectrum of molecule \(\text{V}\) is shown below.
--- 8 WORK AREA LINES (style=blank) --- a.i. Molar mass of \(\text{V}\ = 86\ \text{g mol}^{-1}\) → Indicated by the parent ion peak at 86 m/z. → Molecular formula: \(\ce{C5H10O}\) a.ii. Small peak at m/z = 87: → A carbon-13 isotope being present in the molecule. b. The doublet peak at 1.1 ppm: → Indicates there is a single hydrogen with a different hydrogen environment bonded to an adjacent carbon atom. c. a.i. Molar mass of \(\text{V}\ = 86\ \text{g mol}^{-1}\) → Indicated by the parent ion peak at 86 m/z. → Molecular formula: \(\ce{C5H10O}\) a.ii. Small peak at m/z = 87: → A carbon-13 isotope being present in the molecule. b. The doublet peak at 1.1 ppm: → Indicates there is a single hydrogen with a different hydrogen environment bonded to an adjacent carbon atom. c. From the carbon NMR graph: → There are 4 carbon environments, one shifted above 200 ppm indicating a ketone or aldehyde. → As there are 5 carbons, 2 of the carbons must have the same environment. From the hydrogen NMR graph: → There are 3 hydrogen environments. → The septet peak indicates there are 6 hydrogens with the same chemical environment on adjacent carbon atoms.