Which mixture is best separated into its component parts by fractional distillation?
- Iron filings and sulfur powder
- Ethanol and water
- Oil and vinegar
- Ethane \(\ce{C2H6}\) and octane \(\ce{C8H18}\)
Aussie Maths & Science Teachers: Save your time with SmarterEd
Which mixture is best separated into its component parts by fractional distillation?
\(D\)
\(\Rightarrow D\)
Hexane and water are liquids that are immiscible with each other. Some of their properties are shown in the table.
\begin{array} {|c|c|c|}
\hline & \text{Boiling point } (^{\circ}\text{C}) & \text{Density } (\text{g mL}^{-1})\\
\hline \text{Hexane} & 68.7 & 0.66 \\
\hline \text{Water} & 100 & 1.00 \\
\hline \end{array}
A chemist finds a bottle containing hexane and water and needs to determine whether she should use a separating funnel or distillation to separate the liquids.
Assess the effectiveness of each technique when separating hexane and water. (4 marks)
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A radioisotope \(X\) undergoes alpha decay to form isotope \(Y\).
Isotope \(Y\) then undergoes beta decay to form lead-210.
Which of the following identifies isotope \(X\)?
\(A\)
\(\Rightarrow A\)
The \(^1\)H NMR spectrum of an organic compound has three unique sets of peaks: a single peak, seven peaks (septet) and two peaks (doublet).
The compound is
\(B\)
\(\Rightarrow B\)
Describe the process by which emission line spectra are formed. (4 marks)
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a. \(\alpha < \beta < \gamma\)
b. \(\ce{^222_86Rn -> ^218_84Po + ^4_2He}\)
c. \(\ce{^210_82Pb -> ^210_83Bi + ^0_-1e^-}\)
d. \(\ce{^206_82Pb}\) is a stable isotope.
It has the correct proton-to-neutron ratio, so the nucleus no longer needs to emit radiation to become more stable.
Therefore, the decay chain ends once \(\ce{^206Pb}\) is formed.
a. \(\alpha < \beta < \gamma\)
b. \(\ce{^222_86Rn -> ^218_84Po + ^4_2He}\)
c. \(\ce{^210_82Pb -> ^210_83Bi + ^0_-1e^-}\)
d. \(\ce{^206_82Pb}\) is a stable isotope.
It has the correct proton-to-neutron ratio, so the nucleus no longer needs to emit radiation to become more stable.
Therefore, the decay chain ends once \(\ce{^206Pb}\) is formed.
A calcium ion, \(\ce{Ca^{2+}}\), has an atomic number of 20 and a mass number of 40. Which of the following statements is correct?
\(B\)
\(\Rightarrow B\)
Thorium-232 undergoes a sequence of radioactive decays. In the first part of this sequence, what is the isotope produced when thorium-232 undergoes one alpha decay followed by one beta decay?
\(B\)
\(\Rightarrow B\)
Parking in a city car park is charged at the rate of $3.40 per 20 minutes, or part thereof.
What is the cost of parking for 1 hour and 8 minutes?
`=> B`
`68 -: 20 = 3.4 \ \Rightarrow\ 4\ \text{blocks}`
| `:.\ \text(Cost)` | `= 4 xx 3.40` |
| `= $13.60` |
`=> B`
Which element has the following electronic configuration.
\(1s^2\) \(2s^2\) \(2p^6\) \(3s^2\) \(3p^1\)
\(C\)
\(\Rightarrow C\)
The element tellurium is a brittle, silver-grey metalloid used in solar panels and thermoelectric devices.
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a. \(\ce{^129Te}\)
b. \(\ce{^130_52Te -> ^130_53I + ^0_-1e}\)
a. Let the mass number of the other isotope of Tellurium be \(x\). Therefore:
| \((0.452 \times 126) + (0.548x)\) | \(=127.6\) | |
| \(0.548x\) | \(=70.648\) | |
| \(x\) | \(=128.9 \approx 129\) | |
b. \(\ce{^130_52Te -> ^130_53I + ^0_-1e}\)
Compare and explain the reactivity of Group 1 (alkali metals) and Group 2 (alkaline earth metals) with water. In your answer, link your explanation to electron configuration, atomic radius, and ionisation energy. (6 marks)
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A 5.0 L container is filled with a mixture of milk and coffee in the ratio 3:2.
After removing 1.0 L of the mixture, pure milk is added to refill the container.
What is the ratio of milk to coffee in the final mixture? (3 marks)
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`17:8`
`text{Original mixture amounts}`
`text{Milk : Coffee = 3000 mL : 2000 mL}`
`text{Removing 1.0 L (1000 mL) removes}`
`text{→ }(3/5)×1000=600\text{ mL milk and }(2/5)×1000=400\text{ mL coffee}`
`text{Milk after removal}`
`=3000-600=2400\text{ mL}`
`text{Coffee after removal}`
`=2000-400=1600\text{ mL}`
`text{After refilling with 1000 mL milk:}`
`text{Milk }=2400+1000=3400\text{ mL}`
`text{Coffee }=1600\text{ mL}`
`:.\ \text{Final ratio } \text{Milk : Coffee}`
`=3400:1600`
`=17:8`
`3.4 \ text{km/hr}`
| `text{Actual distance}` | ` =34 times 2000` | |
| `= 68\ 000 \ text{cm}` | ||
| `=680 \ text{m}` | ||
| `= 0.68 \ text{km}` |
`12 \ text{minutes}\ = 12/60 = 0.2 \ text{hours}`
| `text{Speed}` | `= text{distance}/text{time}` | |
| `= 0.68/0.2` | ||
| `= 3.4 \ text{km/hr}` |
The diagrams show two similar shapes. The dimensions of the small shape are enlarged by a scale factor of 1.5 to produce the large shape.
Calculate the area of the large shape. (3 marks)
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`94.5\ text(cm)^2`
`text(Dimension of larger shape:)`
`text(Width) = 6 xx 1.5 = 9\ text(cm)`
`text(Height) = 8 xx 1.5 = 12 \ text(cm)`
`text(Triangle height) = 2 xx 1.5 = 3\ text(cm)`
| `:.\ text(Area)` | `= 9 xx (12-3) + 1/2 xx 9 xx 3` |
| `= 94.5\ text(cm)^2` |
Using your knowledge of the atomic radii for the 2nd and 3rd period elements.
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a. Across Period 2, atomic radius decreases from lithium to neon:
b. Period 3 atomic radii are larger than corresponding Period 2 element:
a. Across Period 2, atomic radius decreases from lithium to neon:
b. Period 3 atomic radii are larger than corresponding Period 2 element:
Explain the trend in electronegativity across a period (from left to right) and down a group in the Periodic Table. Use your knowledge of atomic structure to support your answer. (4 marks)
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Across a period (left to right):
Down a group:
Across a period (left to right):
Down a group:
Which of the following elements has the highest second ionisation energy?
\(A\)
\(\Rightarrow A\)
Explain the relationship between electronegativity and atomic radius with non-metal reactivity down Group 17 (the halogens) of the Periodic Table. (4 marks)
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Ionisation energy is the energy required to remove an electron from an atom.
The table below shows the ionisations energies for element \(\text{Y}\).
\begin{array} {|l|c|c|}
\hline \text{Ionisation energy number} & 1\text{st} & 2\text{nd} & 3\text{rd} & 4\text{th} & 5\text{th} & 6\text{th}\\
\hline \text{Ionisation energy (kJ/mol)} & 738 & 1450 & 7730 & 10\,500 & 13\,600 & 18\,000 \\
\hline \end{array}
Identify the element described by the table.
\(B\)
\(\Rightarrow B\)
A topographic map has a scale of 1 : 250 000.
What is the actual distance between the two lookouts, in kilometres? (1 mark)
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| i. `text{Actual distance (3.6 cm)}` | `= 3.6 xx 250\ 000` |
| `= 900\ 000\ text(cm)` | |
| `= 9\ 000\ text(m)` | |
| `= 9\ text(km)` |
`:.\ text(The 2 lookouts are 9 km apart.)`
ii. `text(Towns are 42.5 km apart.)`
`text{From the scale, } 1\ \text{cm} = 250\ 000\ \text{cm} = 2\ 500\ \text{m} = 2.5\ \text{km}`
`=>\ \text{On the map, } 42.5\ \text{km} = 42.5/2.5 = 17\ \text{cm}`
`:.\ \text{Distance on the map is 17 cm.}`
The capture-recapture technique was used to estimate a population of turtles in 2015.
• 80 turtles were caught, tagged and released.
• Later, 200 turtles were caught at random.
• 40 of these 200 turtles had been tagged.
The estimated population of turtles in 2015 was 25% greater than the estimated population for 2010.
What was the estimated population for 2010? (2 marks)
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`text{320 turtles}`
`text(Let population in 2015 =)\ P(2015)`
`text(Capture)`
`⇒ 80/{P(2015)}`
`text(Recapture)`
`=> 40/200 = 1/5`
| `80/{P(2015)}` | `=1/5` |
| `:. P(2015)` | `= 80 xx 5 =400` |
`text(We know)\ P(2015)\ text(is 25% greater than P(2010))`
| `text{(100% + 25%)} xx P(2010)` | `= 400` |
| `125% xxP(2010)` | `=400` |
| `:. P(2010)` | `=400/1.25` |
| `= 320` |
`:.\ text{2010 population estimate = 320 turtles}`
In a tropical punch, the ratio of passionfruit juice to guava juice to lime juice is 12 : 10 : 6 .
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To completely fill the container with the punch, how many litres of guava juice are required? (3 marks)
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| a. | `text(12 parts)` | `= 2.4\ text(L)` |
| `text(1 part)` | `= 2.4/12` | |
| `= 0.2\ text(L)` |
| `:.\ text(6 parts)` | `= 6 xx 0.2` | |
| `= 1.2\ text(L)` |
| b. | `text{Volume of container}` | `= 40 xx 20 xx 35` |
| `= 28\ 000 \ text{cm}^3` |
`1 \ text{mL} \ to \ 1 \ text{cm}^3`
`⇒ \ 28\ 000 \ text{mL of punch}`
| `therefore \ text{Guava juice required}` | `= text{Guava parts}/text{Total parts} \ xx \ 28\ 000` |
| `= \frac{10}{28} \ xx \ 28\ 000` | |
| `= 10\ 000 \ text{mL}` | |
| `= 10 \ text{L}` |
A toy store releases a limited edition LEGO set for $20 each. At this price, 3000 LEGO sets are sold each week and the revenue is `3000 xx 20=$60\ 000`.
The toy store considers increasing the price. For every dollar price increase, 15 fewer LEGO sets will be sold.
If the toy store charges `(20+x)` dollars for each LEGO set, a quadratic model for the revenue raised, `R`, from selling them is
`R=-15x^2+2700x+60\ 000`
What price should be charged per LEGO set to maximise the revenue? (2 marks)
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How many LEGO sets are sold when the revenue is maximised? (2 marks)
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a. `$110`
b. `1650`
c. `$60\ 000`
a. `text{Highest revenue}\ (R_text{max})\ text(occurs halfway between)\ \ x= -20 and x=200.`
`text{Midpoint}\ =(-20 + 200)/2 = 90`
`:.\ text(Price of LEGO set for)\ R_text(max)`
`=90 + 20`
`=$110`
b. `text{LEGO sets sold when}\ R_{max}`
`=3000-(90 xx 15)`
`=1650`
c. `ytext(-intercept → find)\ R\ text(when)\ \ x=0:`
| `R` | `= -15(0)^2 + 2700(0) + 60\ 000` |
| `=$60\ 000` |
Sage brings 60 cartons of unpasteurised milk to the market each week. Each carton currently sells for $4 and at this price, all 60 cartons are sold each weekend.
Sage considers increasing the price to see if the total income can be increased.
It is assumed that for each $1 increase in price, 6 fewer cartons will be sold.
A graph showing the relationship between the increase in price per carton and the income is shown below.
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The cost of running the market stall is $40 plus $1.50 per carton sold.
Calculate Sage's profit when the income earned from a day selling at the market is maximised. (2 marks)
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a. `$7`
b. `42`
c. `$191`
a. `text(Graph is highest when increase = $3)`
`:.\ text(Carton price)\ = 4 + 3= $7`
b. `text(Cartons sold)\ =60-(3 xx 6)=42`
c. `text{Cost}\ = 42 xx 1.50 + 40 = $103`
`:.\ text(Profit when income is maximised)`
`= (42 xx 7)-103`
`= $191`
The brightness of a lamp \((L)\) is measured in lumens and varies directly with the square of the voltage \((V)\) applied, which is measured in volts.
When the lamp runs at 7 volts, it produces 735 lumens.
What voltage is required for the lamp to produce 1820 lumens? Give your answer correct to one decimal place. (3 marks)
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`11.2\ \text(volts)`
`L prop V^2\ \ => \ \ L=kV^2`
`text(Find)\ k\ \text{given}\ L = 735\ \text{when}\ V = 7:`
| `735` | `= k xx 7^2` |
| `:. k` | `= 735/49=15` |
`text(Find)\ V\ text(when)\ L = 1820:`
| `1820` | `= 15 xx V^2` |
| `V^2` | `= 1820/15=121.33…` |
| `V` | `= sqrt{121.33} = 11.2\ text(volts)\ \ text{(to 1 d.p.)}` |
The following table gives some information about two covalent molecule substances
\begin{array} {|c|c|c|}
\hline \text{Compound} & \text{Molecular formula} & \text{Boiling Point } (^{\circ}C) \\
\hline \text{Water} & \ce{H2O} & 100 \\
\hline \text{Hydrogen sulfide} & \ce{H2S} & -60 \\
\hline \end{array}
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b. Water: Bent and Polar
Hydrogen Sulfide: Bent and polar
c. Even though both molecular are polar:
b. Water: Bent and Polar
Hydrogen Sulfide: Bent and polar
c. Even though both molecular are polar:
Carbon has multiple allotropes. Compare and contrast two allotropes of carbon. (2 marks)
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A population of Tasmanian devils, `D`, is to be modelled using the function `D = 650 (0.8)^t`, where `t` is the time in years.
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a. `650`
b. `416`
c. `text{See Worked Solutions}`
Explain the characteristics of the two oxides given below. (4 marks)
\begin{array} {|c|c|c|}
\hline \text{Compound} & \text{Melting Point } (^{\circ}C) & \text{Conductivity when molten} \\
\hline \ce{XO} & 2850 & \text{good} \\
\hline \ce{YO} & -183 & \text{poor} \\
\hline \end{array}
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\(\ce{XO}\) is an ionic oxide.
\(\ce{YO}\) is a covalent molecular oxide.
\(\ce{XO}\) is an ionic oxide.
\(\ce{YO}\) is a covalent molecular oxide.
Carbon is an important element in industry and biology.
Carbon exists naturally as several allotropes and also has many isotopes. Distinguish between the terms allotrope and isotope, using carbon as an example. (3 marks)
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a.i.
a.ii.
b. Bonding in ionic compounds vs covalent molecular compounds:
c. Differences in boiling points:
a.i.
a.ii.
b. Bonding in ionic compounds vs covalent molecular compounds:
c. Differences in boiling points:
\(D\)
\(\text{By elimination:}\)
\(\text{When}\ x = 0, \ y = 5 \times (0.4)^0 = 5\)
\(\rightarrow\ \text{Eliminate B and C} \)
\(\text{As}\ \ x \rightarrow \infty, \ y \rightarrow 0 \)
\(\rightarrow\ \text{Eliminate A} \)
\(\Rightarrow D\)
The Lewis electron dot diagram of ammonia \(\ce{NH3}\) is shown:
Which of the following is correct for this molecule?
\begin{align*}
\begin{array}{l}
\rule{0pt}{2.5ex} \ \rule[-1ex]{0pt}{0pt}& \\
\rule{0pt}{2.5ex}\textbf{A.}\rule[-1ex]{0pt}{0pt}\\
\rule{0pt}{2.5ex}\textbf{B.}\rule[-1ex]{0pt}{0pt}\\
\rule{0pt}{2.5ex}\textbf{C.}\rule[-1ex]{0pt}{0pt}\\
\rule{0pt}{2.5ex}\textbf{D.}\rule[-1ex]{0pt}{0pt}\\
\end{array}
\begin{array}{|c|c|}
\hline
\rule{0pt}{2.5ex}\text{Molecule polarity}\rule[-1ex]{0pt}{0pt}& \text{Molecular shape} \\
\hline
\rule{0pt}{2.5ex}\text{Non-polar}\rule[-1ex]{0pt}{0pt}&\text{Trigonal Planar}\\
\hline
\rule{0pt}{2.5ex}\text{Non-polar}\rule[-1ex]{0pt}{0pt}& \text{Tetrahedral}\\
\hline
\rule{0pt}{2.5ex}\text{Polar}\rule[-1ex]{0pt}{0pt}& \text{Tetrahedral} \\
\hline
\rule{0pt}{2.5ex}\text{Polar}\rule[-1ex]{0pt}{0pt}& \text{Pyramidal} \\
\hline
\end{array}
\end{align*}
\(D\)
\(\Rightarrow D\)
A wildlife researcher wanted to estimate the number of turtles in a swamp.
She initially caught and tagged 25 turtles before releasing them.
Two weeks later, she caught 50 turtles and found that 10 of them had tags.
What is the best estimate for the total number of turtles in the swamp?
`D`
`text{Let}\ \ T=\ text{population of turtles in swamp}`
`text{Initial tag ratio}\ = 25/T`
`text{Recapture ratio}\ = 10/50`
| `25/T` | `=10/50` |
| `10T` | `=25 xx 50` |
| `T` | `=1250/10` |
| `=125` |
`=> D`
Compare how program customisation approaches differ between recreational participants and elite athletes. (6 marks)
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Benefits
Challenges
Benefits
Challenges
Compare how program customisation approaches differ between recreational participants and elite athletes. (6 marks)
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Similarities
Differences
Similarities
Differences
Two recreational clients complete identical fitness assessments but receive different program recommendations. Client A, who shows excellent motivation but limited time availability, receives a high-intensity interval program. Client B, with more flexible scheduling but lower motivation levels, gets a moderate-intensity continuous training program. This customisation approach primarily demonstrates which principle?
\(C\)
Other Options:
Analyse the relationship between sport-specific assessment and training program effectiveness for elite athletes. (8 marks)
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Overview Statement
Component Relationship 1
Component Relationship 2
Implications and Synthesis
Overview Statement
Component Relationship 1
Component Relationship 2
Implications and Synthesis
Why is continuous monitoring essential for elite athlete program development? (3 marks)
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An elite kickboxer undergoes rigorous testing that reveals a significant strength imbalance, with the dominant leg being much stronger than the non-dominant leg. Which principle of assessment-based program development does addressing this imbalance primarily demonstrate?
\(C\)
Other Options:
How does regular progress monitoring through reassessment enhance program effectiveness for recreational participants? (5 marks)
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Compare how exercise assessments inform program development for recreational participants with different fitness backgrounds and goals. (6 marks)
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Similarities
Differences
Similarities
Differences
A recreational participant focused on weight loss uses regular DEXA scans to track changes in body composition throughout their program. Despite minimal weight changes on scales, the scans show significant increases in lean muscle mass and decreases in fat tissue. This monitoring approach demonstrates which key principle of assessment-based program development?
\(B\)
Other Options:
Discuss the use assistive technology to enhance participation and performance for athletes with disabilities. (6 marks)
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Positive Impacts
Challenges and Limitations
Positive Impacts
Challenges and Limitations
To what extent has GPS tracking technology revolutionised tactical analysis and performance improvement in team sports? (6 marks)
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Judgment Statement
Workload and Tactical Insights
Limitations in Real-Time Application
Reaffirmation
Judgment Statement
Workload and Tactical Insights
Limitations in Real-Time Application
Reaffirmation
Explain how biomechanics analysis tools contribute to improving technique and reducing injury risk in sport. (5 marks)
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Explain how smart resistance training equipment with real-time feedback mechanisms can optimise strength development programs for different athletic populations. (5 marks)
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Which combination of technologies would best help prevent overtraining in an endurance athlete?
\(C\)
Other options:
How do 3D-printed footwear designs most directly enhance performance?
\(A\)
Other options:
Using the substitution \(x=\cos 2 \theta\), show
\(\displaystyle \int \sqrt{\frac{1-x}{1+x}}\,dx=\sqrt{1-x^2}-\cos ^{-1} x+c\) (4 marks)
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\(\text{See worked solutions}\)
\(x=\cos 2 \theta\)
\(\dfrac{dx}{d \theta}=-2 \sin 2 \theta \ \Rightarrow\ \ dx=-2 \sin 2 \theta\, d \theta\)
| \(\displaystyle \int \sqrt{\frac{1-x}{1+x}} \, dx\) | \(=\displaystyle\int \sqrt{\frac{1-\cos 2 \theta}{1+\cos 2 \theta}} \times -2 \sin 2 \theta\, d \theta\) |
| \(=\displaystyle\int \sqrt{\frac{1-\left(2 \cos ^2 \theta-1\right)}{1+\left(2 \cos ^2 \theta-1\right)}} \times -4 \sin \theta \, \cos \theta \, d \theta\) | |
| \(=\displaystyle \int \sqrt{\frac{2\left(1-\cos ^2 \theta\right)}{2 \cos ^2 \theta}} \times-4 \sin \theta \, \cos \theta \, d \theta\) | |
| \(=\displaystyle \int\sqrt{\dfrac{\sin ^2 \theta}{\cos ^2 \theta}} \times-4 \sin \theta \, \cos \theta \, d \theta\) | |
| \(=\displaystyle \int-4 \sin ^2 \theta \, d \theta\) | |
| \(=-4 \displaystyle \int \frac{1-\cos 2 \theta}{2} \,d \theta\) | |
| \(=-2 \displaystyle \int 1-\cos 2 \theta \, d \theta\) | |
| \(=-2 \displaystyle \int 1\, d \theta+2 \int \cos 2 \theta \, d \theta\) | |
| \(=-2 \theta+\sin 2 \theta+c\) | |
| \(=-\cos ^{-1} x+\sqrt{1-\cos ^2 2 \theta}+c \quad \text {(note:}\ \ x=\cos 2 \theta \Rightarrow 2 \theta=\cos ^{-1} x \text{)}\) | |
| \(=-\cos ^{-1} x+\sqrt{1-x^2}+c\) |
The curve \(f(x)=x^2\) is transformed to \(g(x)=3 f[2(x+2)]\)
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a. \(g(x)=12(x+2)^2\)
b. \(\left( -\dfrac{7}{2}, 27 \right) \)
| a. | \(g(x)\) | \(=3[2(x+2)]^2\) |
| \(=3 \times 4(x+2)^2\) | ||
| \(=12(x+2)^2\) |
b. \(P(-3,9)\ \text{lies on}\ \ f(x)=x^2 \)
\(\text{Find corresponding point on}\ f(x)\)
\(\text{Mapping}\ x_f\ \text{to}\ x_g: \)
\(2(x_g +2)=x_f\ \ \Rightarrow\ \ x_g=\dfrac{1}{2} x_f-2 \)
\(x_g=\dfrac {1}{2} \times -3 -2=-\dfrac{7}{2} \)
\(\text{Mapping}\ y_f\ \text{to}\ y_g: \)
\(y_g=3 \times y_f = 3 \times 9=27\)
\(\therefore\ \text{Corresponding point}\ = \left( -\dfrac{7}{2}, 27 \right) \)
Analyse how the relationship between health screening and performance testing contributes to effective exercise program development. (8 marks)
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Overview Statement
Component Relationship 1
Component Relationship 2
Implications and Synthesis
Overview Statement
Component Relationship 1
Component Relationship 2
Implications and Synthesis
A fitness professional completes comprehensive exercise assessments including health screening, performance testing and goal identification before program design. Which factor most critically determines the success of this assessment-based approach?
\(C\)
Other Options:
An endurance runner wants to increase VO₂ max but cannot train at altitude. Which technology best replicates these conditions?
\(B\)
Other options:
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Evaluation Statement
Physiological Restoration
Psychological Resilience
Final Evaluation
Evaluation Statement
Physiological Restoration
Psychological Resilience
Final Evaluation
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Judgment Statement
Long-Term Psychological Value
Immediate Physiological Necessity
Reaffirmation
Judgment Statement
Long-Term Psychological Value
Immediate Physiological Necessity
Reaffirmation
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Process
Physical benefits
Practical application
Process
Physical benefits
Practical application
Which combination of recovery strategies provides the most comprehensive support for both physiological and psychological recovery?
\(A\)
Other options:
Analyse how effective strategy implementation depends on the relationship between individual player roles and overall team objectives in group sports. (8 marks)
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Overview Statement
Component Relationship 1
Component Relationship 2
Implications and Synthesis
Overview Statement
Component Relationship 1
Component Relationship 2
Implications and Synthesis