Steel
Explain how microstructural changes take place in steel when an
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Steel
Explain how microstructural changes take place in steel when an
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→ During hot rolling the steel is heated to above its recrystallisation temperature.
→ Therefore, due to the pressure of the rollers, the grains change from their original state to become elongated.
→ However, as the steel exits the rollers it is still above recrystallisation temperature, resulting in the recrystallisation of the elongated grains to create finer, equiaxed grains.
→ During hot rolling the steel is heated to above its recrystallisation temperature.
→ Therefore, due to the pressure of the rollers, the grains change from their original state to become elongated.
→ However, as the steel exits the rollers it is still above recrystallisation temperature, resulting in the recrystallisation of the elongated grains to create finer, equiaxed grains.
The diagram represents a 120 kg beam that is being guided into place by a crane.
Use a scale drawing to graphically determine the tension in the two cables attached to the beam. (3 marks)
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A solution of hydrochloric acid was standardised by titration against a sodium carbonate solution using the following procedure.
The titration was performed and the hydrochloric acid was found to be 0.200 mol L¯1.
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• A 0.145 g sample of the seashell was placed in a conical flask.
• 50.0 mL of the standardised hydrochloric acid was added to the conical flask.
• At the completion of the reaction, the mixture in the conical flask was titrated with 0.250 mol L¯1 sodium hydroxide.
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a. → Distilled water.
→ This should be used to rinse the conical flask as this will not change the number of moles of
b. 54.3%
a. → Distilled water.
→ This should be used to rinse the conical flask as this will not change the number of moles of
b.
In the event of a fall or a medical emergency, smart watches are designed to alert emergency services when either of the following conditions is met.
Condition 1: the smart watch emergency alert is manually activated
Condition 2: the smart watch detects a sudden fall and no movement for 1 minute
An incomplete logic diagram showing the activation of the smart watch is given.
Complete the diagram by identifying the inputs and drawing the appropriate logic gates. (3 marks)
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A pictorial drawing of an assembled chain master link is shown.
Complete the orthogonal views below, to AS 1100 standards, by adding the following dimensions. (3 marks)
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The following images show an older bus and a contemporary bus.
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i. Toughened glass is formed by:-
→ heating the glass to annealing temperature (approximately 600 degrees) and quenching/rapidly cooling the outside layers using a jet of water.
→ Alternatively toughened glass can be created by soaking the glass in potassium nitrate for an extended period.
ii. Production of curved glass panels:
→ Windscreens are produced by placing a flat sheet of glass above a metal mould.
→ The glass is then evenly heated until it falls and takes the shape of the mould, and then allowed to cool.
→ Once cooled, the glass is then laminated.
→ Laminating involves placing a layer of polymer between two identically shaped sheets of glass, in this case curved windshields.
i. Toughened glass is formed by:-
→ heating the glass to annealing temperature (approximately 600 degrees) and quenching/rapidly cooling the outside layers using a jet of water.
→ Alternatively toughened glass can be created by soaking the glass in potassium nitrate for an extended period.
ii. Production of curved glass panels:
→ Windscreens are produced by placing a flat sheet of glass above a metal mould.
→ The glass is then evenly heated until it falls and takes the shape of the mould, and then allowed to cool.
→ Once cooled, the glass is then laminated.
→ Laminating involves placing a layer of polymer between two identically shaped sheets of glass, in this case curved windshields.
The volume of gas formed at 25°C and 100 kPa as hydrochloric acid was added to a pure sample of aluminium is shown in the graph.
Calculate the original mass of the aluminium sample used in the reaction. (4 marks)
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0.109 grams
→ The graph shows that all the aluminium has reacted when no more gas is being produced, at a volume of 0.150 L.
A spirit burner containing ethanol was used to heat water in a conical flask for three minutes to measure the molar heat of combustion of ethanol.
The results from the investigation are shown.
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This apparatus was set up to produce methyl butanoate.
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a. Flame could ignite one of reagents which is flammable.
b.
c. → Esterification is a relatively slow reaction.
→ Heating the reaction makes it go faster. However, the low boiling points of the reactants make them volatile as they readily convert into gas.
→ The cooling condenser
a. Flame could ignite one of reagents which is flammable.
b.
c. → Esterification is a relatively slow reaction.
→ Heating the reaction makes it go faster. However, the low boiling points of the reactants make them volatile as they readily convert into gas.
→ The cooling condenser
For a particular material, specimens of different sizes were tested. A load-extension diagram and a stress-strain diagram are to be drawn for each specimen.
The shape of which diagram(s) will be affected by the size of the specimen tested?
→ The stress–strain diagrams will be the same shapes as both stress and strain are calculated by dividing by constants (original area and original length).
A gear system for a machine is shown.
What is the speed, in revolutions per minute (rpm), of the driven gear when the driving gear rotates at 1800 rpm?
A pictorial view of a machine component is shown.
When viewed from the direction of arrow A, which drawing correctly shows the half-sectional view?
By Elimination:
→
→ Do not section webs in sectional drawings (eliminate
What feature of fibre optic cables has made them a suitable replacement for traditional copper-based cables?
By Elimination:
→
→
A diode bridge is used to convert AC to DC current.
What type of conversion is this known as?
→ If a diode bridge is used, the conversion will be full wave rectification.
Which of the following identifies two causes of parasitic drag?
→ Parasitic drag is all drag that is caused by the shape, construction-type and material of an aircraft.
What is the thickness of a standard nut that fits a M20 × 2 bolt?
→ AS1100 standards state the width of a nut is 0.8 x the diameter of the bolt.
→ 0.8 × 20 = 16 mm
'Renal dialysis and kidney transplants are very different treatments for the same medical condition. Each treatment was developed from a new application of biological knowledge.'
Justify these statements. (8 marks)
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Consider each element of the statement separately:
Medical Conditions
→ Kidney failure is a recognised medical condition that can be treated using both kidney transplants or renal dialysis.
Different Treatments
→ Renal dialysis is the cleansing of wastes from the blood externally using a dialysis machine.
→ During a kidney transplant the diseased organ is removed and replaced with a healthy organ provided by a donor.
New Application of biological information: Renal dialysis
→ The movement of substances from regions of high concentration to regions of low concentration is known as diffusion.
→ Diffusion can occur across a semi-permeable membrane.
→The dialysis machine allows blood to flow through tubing which is permeable to urea.
→ The solution around the tubing is continually replaced to maintain a steep concentration gradient so the urea can be removed out of the blood through diffusion.
New Application of biological information: Kidney transplant
→ Increased knowledge of the immune system allowed for an improved understanding of organ rejection following organ transplantation.
→ B and T cells on donated organs are recognised by the immune system as foreign and it then attacks the transplanted organ.
→ Once an infection has been removed, suppressor T cells stop the immune cells and switch off the immune response.
→ This knowledge lead to the development of immunosuppressants or anti-rejection drugs designed to fight the immune symptoms’ response to reject donated organs.
→After transplantation, anti-rejection drugs are used by recipients for their lifetime.
Medical Conditions
→ Kidney failure is a recognised medical condition that can be treated using both kidney transplants or renal dialysis.
Different Treatments
→ Renal dialysis is the cleansing of wastes from the blood externally using a dialysis machine.
→ During a kidney transplant the diseased organ is removed and replaced with a healthy organ provided by a donor.
New Application of biological information: Renal dialysis
→ The movement of substances from regions of high concentration to regions of low concentration is known as diffusion.
→ Diffusion can occur across a semi-permeable membrane.
→The dialysis machine allows blood to flow through tubing which is permeable to urea.
→ The solution around the tubing is continually replaced to maintain a steep concentration gradient so the urea can be removed out of the blood through diffusion.
New Application of biological information: Kidney transplant
→ Increased knowledge of the immune system allowed for an improved understanding of organ rejection following organ transplantation.
→ B and T cells on donated organs are recognised by the immune system as foreign and it then attacks the transplanted organ.
→ Once an infection has been removed, suppressor T cells stop the immune cells and switch off the immune response.
→ This knowledge lead to the development of immunosuppressants or anti-rejection drugs designed to fight the immune symptoms’ response to reject donated organs.
→After transplantation, anti-rejection drugs are used by recipients for their lifetime.
The procedure of a first-hand investigation conducted in a school laboratory to determine the percentage of sulfate in a lawn fertiliser is shown.
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a. Modification 1:
→ The
Modification 2:
→ Barium sulfate is a very fine precipitate. By heating the mixture gently for some time, the
Modification 3:
→ The pores of most filter paper are still too large to effectively capture the
Modification 4:
→ Multiple samples of the fertiliser should be analysed and the average value calculated to achieve more valid results. This would mitigate inaccuracies caused by unevenly distributed sulfate in the mixture.
b. 45.9%
a. Modification 1:
→ The
Modification 2:
→ Barium sulfate is a very fine precipitate. By heating the mixture gently for some time, the
Modification 3:
→ The pores of most filter paper are still too large to effectively capture the
Modification 4:
→ Multiple samples of the fertiliser should be analysed and the average value calculated to achieve more valid results. This would mitigate inaccuracies caused by unevenly distributed sulfate in the mixture.
b.
'The application of modern reproductive techniques in plant and animal breeding limits genetic diversity.'
Discuss this statement. (6 marks)
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→ Artificial pollination occurs when humans perform the natural pollination process and transfer the pollen manually to the stigma of one plant from the anther of another.
→ Artificial insemination is the manual transfer of collected semen into the female reproductive system of animals and humans.
→ Both methods can result in an increase in the number of offspring that can be produced by one parent.
→ Whilst the increase in offspring produced may be beneficial, there is also the added risk of reducing the genetic diversity in future populations as one parent can produce many more offspring.
→ On the other hand where species are endangered, or natural processes are interrupted (for example declining bee populations), the techniques provide an opportunity for numbers to stabilise or even increase in subsequent generations.
→ Another advantage is that the process allows for banks of sperm and pollen to be established that can be accessed by other countries, thus creating genetic diversity, by enabling endangered species to survive across continents.
→ Artificial pollination occurs when humans perform the natural pollination process and transfer the pollen manually to the stigma of one plant from the anther of another.
→ Artificial insemination is the manual transfer of collected semen into the female reproductive system of animals and humans.
→ Both methods can result in an increase in the number of offspring that can be produced by one parent.
→ Whilst the increase in offspring produced may be beneficial, there is also the added risk of reducing the genetic diversity in future populations as one parent can produce many more offspring.
→ On the other hand where species are endangered, or natural processes are interrupted (for example declining bee populations), the techniques provide an opportunity for numbers to stabilise or even increase in subsequent generations.
→ Another advantage is that the process allows for banks of sperm and pollen to be established that can be accessed by other countries, thus creating genetic diversity, by enabling endangered species to survive across continents.
The equipment shown is set up. After some time a ring of white powder is seen to form on the inside of the glass tube.
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a. According to Arrhenius:
→ An acid is a solution that produces hydrogen ions when in a solution.
→ A base is a solution that produces hydroxide ions when in a solution.
→ This reaction does not occur in an aqueous solution and would not be an acid-base reaction according to Arrhenius.
b.
→ A Bronsted-Lowry acid donates a proton while a base accepts a proton.
→ This reaction involves proton transfer (
a. According to Arrhenius:
→ An acid is a solution that produces hydrogen ions when in a solution.
→ A base is a solution that produces hydroxide ions when in a solution.
→ This reaction does not occur in an aqueous solution and would not be an acid-base reaction according to Arrhenius.
b.
→ A Bronsted-Lowry acid donates a proton while a base accepts a proton.
→ This reaction involves proton transfer (
A sodium hydroxide solution was titrated against citric acid
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a.
b. Technology solution
→ A digital pH probe could be placed in the flask and used to collect data that plots the pH of the solution against the volume of sodium hydroxide added.
→ The equivalence point would be identified by a steep rise in the pH on the graph.
c.
b. Technology solution
→ A digital pH probe could be placed in the flask and used to collect data that plots the pH of the solution against the volume of sodium hydroxide added.
→ The equivalence point would be identified by a steep rise in the pH on the graph.
c.
Describe the steps involved in the process of addition polymerisation. (3 marks)
Step 1:
→ An organic peroxide (initiator –
→ An unpaired reactive electron can be seen on the end of the growing chain (initiation).
Step 2:
→ The free radical will then attack another ethylene molecule, increasing the length of the growing polymer chain (propagation).
Step 3:
→ Chain length increases in this fashion until two growing chains combine (termination).
Step 1:
→ An organic peroxide (initiator –
→ An unpaired reactive electron can be seen on the end of the growing chain (initiation).
Step 2:
→ The free radical will then attack another ethylene molecule, increasing the length of the growing polymer chain (propagation).
Step 3:
→ Chain length increases in this fashion until two growing chains combine (termination).
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a.
→ Sodium acetate is a basic salt.
→ Acetate is a strong base that accepts a proton, producing hydroxide.
→ The presence of
b.
→ The
→ By Le Chatelier’s principle, this will subsequently move the reaction to the left to increase the
a.
→ Sodium acetate is a basic salt.
→ Acetate is a strong base that accepts a proton, producing hydroxide.
→ The presence of
b.
→ The
→ By Le Chatelier’s principle, this will subsequently move the reaction to the left to increase the
The table shows the heat of combustion of four straight chain alkanols.
What is the mass of water that could be heated from 20°C to 45°C by the complete combustion of 1.0 g of heptan-1-ol?
Question 18
How could the reliability of the analysis of the pond water be improved?
Question 19
What was the concentration of lead ions in the sample?
Question 18
Question 19
A group of students hypothesised that the height of plants decreases with increased elevation.
The students planted ten plant cuttings from the same plant at each of five locations. The locations were at varying elevations in the same mountain range. All the cuttings were provided with the same volume of water on planting, and no fertiliser was applied. The students returned after the same growth period and measured the height of the plants.
The cross-section shown indicates the average height of the plants in metres after the growth period at each location in the mountain range.
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a. Factors affecting experiment validity:
→ There are many variables in this experiment that are not controlled, hence the experiment is invalid.
→ There is no real evidence that the differences in plant heights observed in the different locations are due to elevation alone.
→ Variables with adequate controls in the experiment include planting methods and genotype.
→ Factors other than these can affect plant growth and should have been considered.
→ Variables not controlled well include exposure to the prevailing wind, available sunlight at the various locations and size and health of cuttings at time of planting.
b. Mountain Range cross-section data
a. Factors affecting experiment validity:
→ There are many variables in this experiment that are not controlled, hence the experiment is invalid.
→ There is no real evidence that the differences in plant heights observed in the different locations are due to elevation alone.
→ Variables with adequate controls in the experiment include planting methods and genotype.
→ Factors other than these can affect plant growth and should have been considered.
→ Variables not controlled well include exposure to the prevailing wind, available sunlight at the various locations and size and health of cuttings at time of planting.
b. Mountain Range cross-section data
The diagram shows a model involving DNA.
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a. DNA replication
b. Successful answers should include two of the following:
→ the double helix.
→ the sugar-phosphate backbone.
→ hydrogen bonds (connecting base pairs)
a. DNA replication
b. Successful answers should include two of the following:
→ the double helix.
→ the sugar-phosphate backbone.
→ hydrogen bonds (connecting base pairs)
Refer to the following information to answer Questions 19 and 20 .
The intestinal tract of a human foetus is sterile.
After birth, microflora from the mother are transferred to the baby's mouth through close contact. After a year, the microflora of the baby is similar to the mother's, with the baby's immune system ignoring these microbes.
Also during the first year of life, breast milk from the mother provides antibodies to the baby for any disease the mother has already experienced. When breastfeeding ceases, these antibody levels in the baby start to fall.
After the first year, any new species of invading bacteria is treated as a pathogen by the baby's immune system.
Question 19
A medical consequence for six-month-old babies that have only been bottle-fed with formula milk and not breastfed is that
Question 20
Strict hygiene practices are followed in the care of newborns, whereas hygiene practices in the care of older babies are less emphasised.
Which of the following is the best reason for this difference?
Q19.
Q20.
Q 19.
→ Bottle fed babies will not have the added immunity that is provided by the mother’s breast milk.
→ They will therefore have immune systems that are more susceptible to infectious disease.
Q20.
→ The immune systems of newborns will not work as efficiently as that of older babies as their immune systems are underdeveloped.
Refer to the following information to answer Questions 12 and 13.
Question 12
Which reason best explains why the corresponding control measure reduces this problem?
Question 13
The following measures could be used to prevent the spread of this fruit fly across Australia.
To prevent the spread of this fruit fly across Australia, which combination of measures would be most practical to use?
Q12.
Q13.
Q12.
→ Future generations of flies will eventually be reduced in numbers and may even be wiped out altogether.
Q13.
→ It may be possible to contain the outbreak to local areas by restricting the movement of affected fruit to other states and countries, thus making it easier to manage.
Refer to the following information to answer Questions 7 and 8 .
The diagram shows a homeostatic mechanism in a mammal.
Question 7
What does
Question 8
Which of the following describes what happens to the muscles and the arteriole walls in the skin when the core body temperature is below normal?
Q7.
Q8.
Q7.
→ Messages are sent by the brain to the effectors.
→ This promotes a stimulus response.
Q8. When body temperature is below normal:
→ Hairs stand on end and arteriole walls of skin contract to prevent the loss of heat.
Which of the following solutions has the highest pH?
By Elimination:
→ Acetic acid is weaker than hydrochloric acid and therefore has a higher pH (eliminate C and D).
→ A more dilute acid has a higher pH (eliminate A).
The molar heat of combustion
Calculate the energy generated per kg of
Outline TWO advantages and TWO disadvantages of using ethanol as an alternative fuel for motor vehicles. (4 marks)
Advantages:
→ Ethanol can be produced from biomass. These renewable sources include crops such as sugarcane as opposed to other fuels such as petrol which come from non-renewable fossil fuels, which are finite resources.
→ Ethanol undergoes complete combustion more easily than octane, producing less soot
Disadvantages:
→ Ethanol releases less energy, on a mole or per kilogram basis, than octane. This results in a greater mass of fuel being required to supply an equivalent amount of energy.
→ Producing ethanol from renewable crops requires a huge amount of arable land. This reduces the availability of land for other crops.
Advantages:
→ Ethanol can be produced from biomass. These renewable sources include crops such as sugarcane as opposed to other fuels such as petrol which come from non-renewable fossil fuels, which are finite resources.
→ Ethanol undergoes complete combustion more easily than octane, producing less soot
Disadvantages:
→ Ethanol releases less energy, on a mole or per kilogram basis, than octane. This results in a greater mass of fuel being required to supply an equivalent amount of energy.
→ Producing ethanol from renewable crops requires a huge amount of arable land. This reduces the availability of land for other crops.
The boiling points and molar masses of three compounds are shown in the table.
Acetic acid, butan-1-ol and butyl acetate have very different molar masses but similar boiling points. Explain why in terms of the structure and bonding of the three compounds. (5 marks)
→ Although the three listed compounds different molar masses, they have similar boiling points due to their different structures and resulting intermolecular forces.
→ Butyl acetate has the largest molar mass and therefore greatest dispersion forces but it is only slightly polar and has no hydrogen bonding.
→ Butan-1-ol has lower molar mass than butyl acetate and therefore smaller dispersion forces but it is polar and contains a hydrogen bound to an oxygen. Therefore, it exhibits hydrogen bonding resulting in strong intermolecular forces and a boiling point in the middle of the three compounds.
→ Acetic acid has the lowest molar mass and hence the weakest dispersion forces. It is however highly polar due to the presence of the carboxyl group
→ The presence of a second oxygen in acetic acid increases the hydrogen bonding compared with butan-1-ol.
→ These factors lead to acetic acid possessing the highest boiling point despite its molar mass being the lowest.
→ In summary, the totality of the intermolecular forces of all three molecules is similar and therefore similar boiling points.
→ Although the three listed compounds different molar masses, they have similar boiling points due to their different structures and resulting intermolecular forces.
→ Butyl acetate has the largest molar mass and therefore greatest dispersion forces but it is only slightly polar and has no hydrogen bonding.
→ Butan-1-ol has lower molar mass than butyl acetate and therefore smaller dispersion forces but it is polar and contains a hydrogen bound to an oxygen. Therefore, it exhibits hydrogen bonding resulting in strong intermolecular forces and a boiling point in the middle of the three compounds.
→ Acetic acid has the lowest molar mass and hence the weakest dispersion forces. It is however highly polar due to the presence of the carboxyl group
→ The presence of a second oxygen in acetic acid increases the hydrogen bonding compared with butan-1-ol.
→ These factors lead to acetic acid possessing the highest boiling point despite its molar mass being the lowest.
→ In summary, the totality of the intermolecular forces of all three molecules is similar and therefore similar boiling points.
A solution of sodium hydroxide was titrated against a standardised solution of acetic acid which had a concentration of 0.5020 mol L¯1.
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a.
b.
→ The acetate ion is a weak base.
→ As a result, it has accepted a proton from the water resulting in production of hydroxide ions.
→ Therefore the solution has a pH > 7.
a.
b.
→ The acetate ion is a weak base.
→ As a result, it has accepted a proton from the water resulting in production of hydroxide ions.
→ Therefore the solution has a pH > 7.
The following reaction scheme can be used to synthesise ethyl ethanoate.
Outline the reagents and conditions required for each step and how the product of each step could be identified. (7 marks)
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Step 1:
→ To synthesise chloroethane (A) into ethanol (B),
→ The mixture is then treated with concentrated sulfuric acid and refluxed.
→ Ethanol (B) can be identified using infrared spectroscopy by looking for a broad absorption between 3230 cm ¯1 and 3550 cm ¯1, which indicates the presence of an
→ Alternative ways to identify ethanol include: mass spectrum analysis (single ion peak at m/z = 46), reactivity tests, and
Step 2:
→ Ethanol (B) can be converted into ethanoic acid (C) by combining it with a strong oxidant like sodium carbonate, which produces carbon dioxide bubbles, confirming the presence of a carboxylic acid.
→ Ethanol will not react as above and the compounds can be distinguished.
→ Alternative ways to identify ethanoic acid include: IR or
Step 3
→ Ethyl ethanoate (D) can be synthesised by heating a mixture of ethanol, ethanoic acid and concentrated sulfuric acid under reflux.
→ A
→ Alternative ways to identify ethyl ethanoate include: a distinct smell, no
Step 1:
→ To synthesise chloroethane (A) into ethanol (B),
→ The mixture is then treated with concentrated sulfuric acid and refluxed.
→ Ethanol (B) can be identified using infrared spectroscopy by looking for a broad absorption between 3230 cm ¯1 and 3550 cm ¯1, which indicates the presence of an
→ Alternative ways to identify ethanol include: mass spectrum analysis (single ion peak at m/z = 46), reactivity tests, and
Step 2:
→ Ethanol (B) can be converted into ethanoic acid (C) by combining it with a strong oxidant like sodium carbonate, which produces carbon dioxide bubbles, confirming the presence of a carboxylic acid.
→ Ethanol will not react as above and the compounds can be distinguished.
→ Alternative ways to identify ethanoic acid include: IR or
Step 3
→ Ethyl ethanoate (D) can be synthesised by heating a mixture of ethanol, ethanoic acid and concentrated sulfuric acid under reflux.
→ A
→ Alternative ways to identify ethyl ethanoate include: a distinct smell, no
Stormwater from a mine site has been found to be contaminated with copper
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a. Recommended Treatment:
→ Calcium hydroxide is a slightly soluble compound, while copper
→ When these compounds are added to water, the metal ions tend to precipitate out of solution.
→ For example, the addition of solid calcium hydroxide to water produces calcium ions
→ These reactions are represented by the equations:
b. Atomic absorption spectroscopy (AAS):
→ Can be used for determining the concentration of metal ions in a sample by measuring the absorbance of light at specific wavelengths that are characteristic of each metal.
→ AAS uses light wavelengths that correspond to atomic absorption by the element of interest, and since each element has unique wavelengths that are absorbed, the concentration of that element can be selectively measured in the presence of other species.
→ As a result, AAS can be used to independently measure the concentrations of different metal ions, such as lead
c. Concentrations of ions:
→ Concentrations of copper and lead have been significantly reduced.
→ Convert concentrations to compare with standard:
Conclusion:
→ The concentration of copper ions has been reduced to a level that is lower than the discharge limit (0.16 < 1.0) but the lead ion concentration has not (1.76 > 1.0).
→ The treatment has only been partially successful.
a. Recommended Treatment:
→ Calcium hydroxide is a slightly soluble compound, while copper
→ When these compounds are added to water, the metal ions tend to precipitate out of solution.
→ For example, the addition of solid calcium hydroxide to water produces calcium ions
→ These reactions are represented by the equations:
b. Atomic absorption spectroscopy (AAS):
→ Can be used for determining the concentration of metal ions in a sample by measuring the absorbance of light at specific wavelengths that are characteristic of each metal.
→ AAS uses light wavelengths that correspond to atomic absorption by the element of interest, and since each element has unique wavelengths that are absorbed, the concentration of that element can be selectively measured in the presence of other species.
→ As a result, AAS can be used to independently measure the concentrations of different metal ions, such as lead
c. Concentrations of ions:
→ Concentrations of copper and lead have been significantly reduced.
→ Convert concentrations to compare with standard:
Conclusion:
→ The concentration of copper ions has been reduced to a level that is lower than the discharge limit (0.16 < 1.0) but the lead ion concentration has not (1.76 > 1.0).
→ The treatment has only been partially successful.
Assess the usefulness of the Brønsted-Lowry model in classifying acids and bases. Support your answer with at least TWO chemical equations. (5 marks)
→ The Bronsted-Lowry model is a way of classifying acids and bases based on their ability to donate or accept protons.
→ This model is more comprehensive than the Arrhenius model, as it can explain the acid-base behaviour of more species, including those that do not contain
→ Consider the reaction
→ However, the Bronsted-Lowry model does have some limitation, such as its inability to explain the acidity of certain acidic oxides and their reactions with basic oxides.
→ e.g.
→ The Bronsted-Lowry model is a way of classifying acids and bases based on their ability to donate or accept protons.
→ This model is more comprehensive than the Arrhenius model, as it can explain the acid-base behaviour of more species, including those that do not contain
→ Consider the reaction
→ However, the Bronsted-Lowry model does have some limitation, such as its inability to explain the acidity of certain acidic oxides and their reactions with basic oxides.
→ e.g.
The relationship between the acid dissociation constant,
Assume that the temperature for part (a) and part (b) is 25°C.
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a.
b.
Assume
Which of the equations correctly describes incomplete combustion?
→ Incomplete combustion produces carbon and/or carbon monoxide (eliminate B and C).
→ Option D is not balanced (oxygen atoms do not equate)
20.0 mL of 0.020 mol L¯1 barium hydroxide solution is added to 50.0 mL of 0.040 mol L¯1 hydrochloric acid solution.
What is the pH of the final solution?
Three gases
Which reaction is represented by the graph?
Concentration changes at T:
→ Concentrations of X ↓ 25%, Y ↓ 25%, Z ↓ 25%
New equilibrium after T:
→ Concentrations of X ↓ 0.005 mol L ¯1, Y ↑ 0.005 mol L ¯1, Z ↑ 0.005 mol L ¯1
→ Shift is equimolar (1:1:1) and Y and Z are on the same side of the equation (both increase)
The following equilibrium is established in a closed system.
How can the gas pressure in the system be decreased?
→ Gas pressure can be decreased if the equilibrium shifts to the right.
→ If hydroxide ions are added to the solution by adding NaOH, this will neutralise the carbonic acid and cause an equilibrium shift to the right.
One litre of an aqueous solution is formed from mixing equal volumes of 0.2 mol L
How effective as a buffer is the aqueous solution formed?
→
→ Aqueous solution formed will be ineffective as a buffer (no equilibrium in solution will be formed).
What is the product when propene undergoes addition polymerisation?
Polymerisation of propene:
→ No double bonds (eliminate A and C)
→ Methyl functional group appear on every second carbon atom
There are two unlabelled solutions. One is barium nitrate and the other lead nitrate.
Which of the following could be added to the two unlabelled solutions to distinguish between them?
→ If sodium chloride is added to barium nitrate, barium chloride (soluble) is formed but no precipitate results.
→ If sodium chloride is added to lead nitrate, lead chloride (insoluble) is formed and a precipitate results.
→ All other options will produce either a precipitate or no precipitate in both solutions and not distinguish between them.
Three test tubes were set up as shown.
Bromine water was added to
Which of the following best represents the changes in test tubes
By Elimination:
→ Liquids are immiscible (eliminate A and D).
→ Bromine water does not decolourise with with alkanes, but does with alkenes (eliminate B).
Which defence adaptation in the table is correctly matched with one of its features?
→ In some cases, such as in response to leprosy or tuberculosis, the body seals off a pathogen by forming a granuloma, a collection of cells containing macrophages, lymphocytes then fibroblasts (a structural cell involved in connective tissue), which forms a tough outer wall.
In the Large Hadron Collider (LHC), protons travel in a circular path at a speed greater than 0.9999
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a. Advantages:
→ Strong magnetic fields are necessary to deflect protons travelling around the LHC due to their high velocities and the effect of mass dilation.
→ Superconductors can achieve very high current flow. This produces the very strong magnetic fields that are required.
b. Applications of special relativity:
→ Since the protons are travelling so close to the speed of light, special relativity states that mass dilation will be significant.
→ This effect means that an increasing amount of energy is needed to accelerate the proton.
Other answers could include:
→ Effects of length contraction/time dilation.
→ Identification of the non-inertial frame of reference.
a. Advantages:
→ Strong magnetic fields are necessary to deflect protons travelling around the LHC due to their high velocities and the effect of mass dilation.
→ Superconductors can achieve very high current flow. This produces the very strong magnetic fields that are required.
b. Applications of special relativity:
→ Since the protons are travelling so close to the speed of light, special relativity states that mass dilation will be significant.
→ This effect means that an increasing amount of energy is needed to accelerate the proton.
Other answers could include:
→ Effects of length contraction/time dilation.
→ Identification of the non-inertial frame of reference.
Consider the following two models used to calculate the work done when a 300 kg satellite is taken from Earth's surface to an altitude of 200 km.
You may assume that the calculations are correct.
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a. Model
→ Assumes Earth’s gravitational field strength remains constant moving upwards from the surface.
Model
→ Assumes Earth’s gravitational field strength changes with altitude.
b. Similarity of results due to:
→ The variation in gravitational field strength from Earth’s surface to an altitude of 200 km is minimal, so both models
c.
a. Model
→ Assumes Earth’s gravitational field strength remains constant moving upwards from the surface.
Model
→ Assumes Earth’s gravitational field strength changes with altitude.
b. Similarity of results due to:
→ The variation in gravitational field strength from Earth’s surface to an altitude of 200 km is minimal, so both models
c. Centripetal force = force due to gravity:
The diagram shows a label on a transformer used in an appliance.
Explain why the information provided on the label is not correct. Support your answer with calculations. (3 marks)
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Calculating the input power:
Calculating the output power:
→ The output power is greater than the input power.
→ The label is incorrect as this is inconsistent with the law of conservation of energy.
Calculating the input power:
Calculating the output power:
→ The output power is greater than the input power.
→ The label is incorrect as this is inconsistent with the law of conservation of energy.
A projectile was launched from the ground. It had a range of 70 metres and was in the air for 3.5 seconds.
At what angle to the horizontal was it launched?
Find
Find
Find launch angle:
The diagram shows an ideal transformer.
When the switch is closed, the pointer on the galvanometer deflects.
How could the size of the deflection be increased?
In order to increase the deflection of the galvanometer, the current through the secondary coil must increase.
→ Decreasing the number of secondary coils will decrease
→ Decreasing the number of secondary coils will increase
A circular loop of wire is stationary in a magnetic field. The sides are then pushed together to change the shape, as shown in the diagram.
As the loop is compressed, a current is induced.
Which row of the table shows the direction of the current and explains why it is induced?
→ Compressing the loop decreases the area of the loop.
→ There is a change (reduction) in magnetic flux passing through the loop.
→ A current is generated in the loop in order to mitigate this change by producing a magnetic field directed into the page.
→ Using the right hand grip rule, the current direction is clockwise.
A simple AC generator was connected to a cathode ray oscilloscope and the coil was rotated at a constant rate. The output is shown on this graph.
Which of the following graphs best represents the output if the rate of rotation is decreased to half of the original value?
Halving the rate of rotation of the bar magnet:
→ Doubles the period of the output graph (eliminate A and B).
→ Halves the rate of change of flux through the coil of the generator.
→ Halves of the maximum output voltage.
What is the net force on conductor
→ As the currents in
→ As the currents in
→ The force on
→ The force on
→
→ The net force on
A current-carrying wire is placed perpendicular to a magnetic field.
Which graph correctly shows the relationship between magnetic field strength
→ If
→ i.e. there is an inverse relationship between
Which of the following is a true statement about scientific theories, such as Einstein's theory of special relativity?
By Elimination:
→ Scientific theories are supported by experiments that when performed yield similar results (reliability). Examples include observations of muons and atomic clock experiments for Einstein’s theory of special relativity (eliminate A and C).
→ Scientific theories have large amounts of supporting evidence and are accepted (eliminate D).
The following makeshift device was made to provide lighting for a stranded astronaut on Mars.
The mass of Mars is
The 2 kg mass falls, turning the DC generator, which supplies energy to the light bulb. The mass falls from a point that is 3 376 204 m from the centre of Mars.
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a. 7.48 J
b. When switch is opened:
→ When the switch is opened, there is no induced current opposing the downwards motion of the mass (Lenz’s Law).
→ Hence, the mass will fall more quickly.
a.
→ 7.48 J is lost by the falling mass.
→ The light bulb released 7.48 J of energy.
b. When switch is opened:
→ When the switch is opened, there is no induced current opposing the downwards motion of the mass (Lenz’s Law).
→ Hence, the mass will fall more quickly.
The following diagram shows the acceleration of a rocket during the first stage of its launch.
Explain the acceleration of the rocket with reference to the law of conservation of momentum. (5 marks)
→ The combustion of fuel and expulsion of gases causes propulsion of the rocket. The rocket exerts a force on these gases in order to expel them backwards.
→ An equal and opposite force is exerted back on the rocket by the gases (Newton’s Third Law).
→ As the rocket and gases form a closed system, the law of conservation of momentum applies, meaning the momentum of the rocket is equal in magnitude and opposite in direction to the momentum of the fuel.
→ The momentum of the rocket is given by
→ The rocket will accelerate. Also, using
→ The combustion of fuel and expulsion of gases causes propulsion of the rocket. The rocket exerts a force on these gases in order to expel them backwards.
→ An equal and opposite force is exerted back on the rocket by the gases (Newton’s Third Law).
→ As the rocket and gases form a closed system, the law of conservation of momentum applies, meaning the momentum of the rocket is equal in magnitude and opposite in direction to the momentum of the fuel.
→ The momentum of the rocket is given by
→ The rocket will accelerate. Also, using